About: Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X     Goto   Sponge   NotDistinct   Permalink

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  • It was demonstrated that the behaviour of polar group X in the compounds of the type [2,6-(Me2NCH2)2C6H3]SbX2 has a crucial effect on the geometry around the central antimony atom. The shapes of coordination polyhedron range from a bicapped - trigonal pyramid (X = CH3COO), and a distorted tetragonal pyramid (X = CF3COO) to a psí-trigonal bipyramid (X = Cl, CB11H12). Even more, an unusual dinuclear ionic complex was prepared and characterized and in this case the structure of the organometallic cation can be described as one apex sharing distorted tetragonal pyramids.
  • It was demonstrated that the behaviour of polar group X in the compounds of the type [2,6-(Me2NCH2)2C6H3]SbX2 has a crucial effect on the geometry around the central antimony atom. The shapes of coordination polyhedron range from a bicapped - trigonal pyramid (X = CH3COO), and a distorted tetragonal pyramid (X = CF3COO) to a psí-trigonal bipyramid (X = Cl, CB11H12). Even more, an unusual dinuclear ionic complex was prepared and characterized and in this case the structure of the organometallic cation can be described as one apex sharing distorted tetragonal pyramids. (en)
Title
  • Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X
  • Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X (en)
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  • Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X
  • Structural study on the organoantimony(III) NCN - Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 - Influence of the polar group X (en)
skos:notation
  • RIV/00216275:25310/10:39881463!RIV11-GA0-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GP203/07/P094), Z(MSM0021627501), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika
  • 3
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  • 290453
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  • RIV/00216275:25310/10:39881463
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  • group; polar; the; Influence; [2,6-(Me2NCH2)2C6H3]SbX2; compounds; Chelated; NCN; organoantimony(III); the; study; Structural (en)
http://linked.open.../riv/klicoveSlovo
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  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [0825F3DAB194]
http://linked.open...i/riv/nazevZdroje
  • Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...v/svazekPeriodika
  • 695
http://linked.open...iv/tvurceVysledku
  • Dostál, Libor
  • Jambor, Roman
  • Padělková, Zdeňka
  • Růžička, Aleš
  • Jirásko, Robert
  • Holeček, Jaroslav
http://linked.open...ain/vavai/riv/wos
  • 000273782000012
http://linked.open...n/vavai/riv/zamer
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  • 0022-328X
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  • 25310
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