About: Optical band gap and Raman spectra in some (Bi2O3)(x)(WO3)(y)(TeO2)(100-x-y) and (PbO)(x)(WO3)(y)(TeO2)(100-x-y) glasses     Goto   Sponge   NotDistinct   Permalink

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Description
  • The glasses representing (Bi2O3)(x)(WO3)(y)(TeO2)(100-x-y) and (PbO)(x)(WO3)(y)(TeO2)(100-x-y) systems were prepared. The dilatometric glass-transition temperatures of examined glass samples were found in the region 383-434 degrees C, the coefficient of thermal expansion varied from 12 to 16 ppm/degrees C and the density ranged from 6.30(2) to 6.80(8) g/cm(3). From the optical transmission measurements of thin glassy bulk samples prepared by a glass blowing, the optical gap values were found in the narrow region 3.21-3.36 eV. For the temperature interval 300-480 K, the values of the temperature coefficient of the optical band gap varied from 3.7 x 10(-4) to 5.24 x 10(-4) eV/K. It is suggested that Raman feature observed at around 350 cm(-1) can be assigned to an overlap of Raman bands attributed to WO6 corner shared octahedra and to the following three atomic linkages: Bi-O-Te, Pb-O-Te and W-O-Te. (C) 2009 Elsevier B.V. All rights reserved.
  • The glasses representing (Bi2O3)(x)(WO3)(y)(TeO2)(100-x-y) and (PbO)(x)(WO3)(y)(TeO2)(100-x-y) systems were prepared. The dilatometric glass-transition temperatures of examined glass samples were found in the region 383-434 degrees C, the coefficient of thermal expansion varied from 12 to 16 ppm/degrees C and the density ranged from 6.30(2) to 6.80(8) g/cm(3). From the optical transmission measurements of thin glassy bulk samples prepared by a glass blowing, the optical gap values were found in the narrow region 3.21-3.36 eV. For the temperature interval 300-480 K, the values of the temperature coefficient of the optical band gap varied from 3.7 x 10(-4) to 5.24 x 10(-4) eV/K. It is suggested that Raman feature observed at around 350 cm(-1) can be assigned to an overlap of Raman bands attributed to WO6 corner shared octahedra and to the following three atomic linkages: Bi-O-Te, Pb-O-Te and W-O-Te. (C) 2009 Elsevier B.V. All rights reserved. (en)
Title
  • Optical band gap and Raman spectra in some (Bi2O3)(x)(WO3)(y)(TeO2)(100-x-y) and (PbO)(x)(WO3)(y)(TeO2)(100-x-y) glasses
  • Optical band gap and Raman spectra in some (Bi2O3)(x)(WO3)(y)(TeO2)(100-x-y) and (PbO)(x)(WO3)(y)(TeO2)(100-x-y) glasses (en)
skos:prefLabel
  • Optical band gap and Raman spectra in some (Bi2O3)(x)(WO3)(y)(TeO2)(100-x-y) and (PbO)(x)(WO3)(y)(TeO2)(100-x-y) glasses
  • Optical band gap and Raman spectra in some (Bi2O3)(x)(WO3)(y)(TeO2)(100-x-y) and (PbO)(x)(WO3)(y)(TeO2)(100-x-y) glasses (en)
skos:notation
  • RIV/00216275:25310/09:00008639!RIV12-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40500505), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 45-47
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 331804
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/09:00008639
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Raman spectroscopy; Optical spectroscopy; Heavy-metal oxides; Raman scattering (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [87DF8A9A42D2]
http://linked.open...i/riv/nazevZdroje
  • Journal of Non-Crystalline Solids
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 355
http://linked.open...iv/tvurceVysledku
  • Tichý, Ladislav
  • Tichá, Helena
  • Ožďanová, Jitka
http://linked.open...ain/vavai/riv/wos
  • 000271361300021
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-3093
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jnoncrysol.2009.07.004
http://localhost/t...ganizacniJednotka
  • 25310
is http://linked.open...avai/riv/vysledek of
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