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  • Diafiltration is used to allow a high level of desalting to be achieved. However, the success of the application of NF for the desalting is related, among other factors, with magnitude of the permeate fluxes decline. We show that the dye and salt concentration, the salt rejection and pressure applied are responsible for the decrease of flux values as well as for desalting purposes. We found in the process of desalination of aqueous dye-salt solutions by polymeric NF membranes that cake layer formation of dye molecules on membrane surface, especially at low salt concentrations, was the principal cause of flux decline. Results demonstrate how the mathematical modelling of NF and description of discontinuous diafiltration by periodically adding solvent at constant pressure difference can be important for prediction of the diafiltration process in the manufacture of liquid dyes.
  • Diafiltration is used to allow a high level of desalting to be achieved. However, the success of the application of NF for the desalting is related, among other factors, with magnitude of the permeate fluxes decline. We show that the dye and salt concentration, the salt rejection and pressure applied are responsible for the decrease of flux values as well as for desalting purposes. We found in the process of desalination of aqueous dye-salt solutions by polymeric NF membranes that cake layer formation of dye molecules on membrane surface, especially at low salt concentrations, was the principal cause of flux decline. Results demonstrate how the mathematical modelling of NF and description of discontinuous diafiltration by periodically adding solvent at constant pressure difference can be important for prediction of the diafiltration process in the manufacture of liquid dyes. (en)
Title
  • Evaluation of nanofiltration for diafiltration of dyes solutios: Experimental observations and model evaluation
  • Evaluation of nanofiltration for diafiltration of dyes solutios: Experimental observations and model evaluation (en)
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  • Evaluation of nanofiltration for diafiltration of dyes solutios: Experimental observations and model evaluation
  • Evaluation of nanofiltration for diafiltration of dyes solutios: Experimental observations and model evaluation (en)
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  • RIV/00216275:25310/09:00008623!RIV10-MSM-25310___
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  • Z(MSM0021627502)
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  • 313884
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  • RIV/00216275:25310/09:00008623
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  • Nanofiltration; Diafiltration; Reactive dyes; Dye desalination (en)
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  • [5F0633DBE52D]
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  • Praha
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  • Praha
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  • Proceedings of the PERMEA 2009
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  • Mikulášek, Petr
  • Cuhorka, Jiří
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number of pages
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  • Ústav makromolekulární chemie AV ČR
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  • 978-80-85009-58-3
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  • 25310
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