About: cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX), its properties and initiation reactivity     Goto   Sponge   NotDistinct   Permalink

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  • Using the 15N NMR chemical shifts of nitrogen atoms in nitramino groups of bicyclo HMX or BCHMX and additional 10 nitramines,we have assessed its reactivity in detonation,under the influence of impact,and by action of electric spark.It is stated that the thermal stability of BCHMX is higher than that of RDX.The longest N-N bond in the BCHMX molecule (1.412(4) Å) is the cause of its higher impact reactivity,which is at the level of that of PETN. In the experimentally determined detonation velocity,BCMX can be slightly better as RDX. From the standpoint of friction sensitivity,BCHMX is close to HMX. Attention was also focused upon the solubility-temperature dependence of BCHMX in acetone,acetonitrile,ethyl acetate,dimethyl sulfoxide,tetrahydrofurane,and nitromethane.X-Ray crystallographic study of BCHMX (C4H6N8O8, Mr = 294.17),has been carried at the temperature of 150 K.There were found in the BCHMX molecular crystal more short contacts in the new structure making extensive supramolecular architec
  • Using the 15N NMR chemical shifts of nitrogen atoms in nitramino groups of bicyclo HMX or BCHMX and additional 10 nitramines,we have assessed its reactivity in detonation,under the influence of impact,and by action of electric spark.It is stated that the thermal stability of BCHMX is higher than that of RDX.The longest N-N bond in the BCHMX molecule (1.412(4) Å) is the cause of its higher impact reactivity,which is at the level of that of PETN. In the experimentally determined detonation velocity,BCMX can be slightly better as RDX. From the standpoint of friction sensitivity,BCHMX is close to HMX. Attention was also focused upon the solubility-temperature dependence of BCHMX in acetone,acetonitrile,ethyl acetate,dimethyl sulfoxide,tetrahydrofurane,and nitromethane.X-Ray crystallographic study of BCHMX (C4H6N8O8, Mr = 294.17),has been carried at the temperature of 150 K.There were found in the BCHMX molecular crystal more short contacts in the new structure making extensive supramolecular architec (en)
Title
  • cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX), its properties and initiation reactivity
  • cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX), its properties and initiation reactivity (en)
skos:prefLabel
  • cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX), its properties and initiation reactivity
  • cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX), its properties and initiation reactivity (en)
skos:notation
  • RIV/00216275:25310/09:00008582!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 2-3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 307183
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/09:00008582
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole; detonation; initiation; sensitivity; solubility (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [3CF0F1E2E080]
http://linked.open...i/riv/nazevZdroje
  • Journal of Hazardous Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 164
http://linked.open...iv/tvurceVysledku
  • Růžička, Aleš
  • Zeman, Svatopluk
  • Jungová, Marcela
  • KLASOVITÝ, Dušan
  • Roháč, Michal
http://linked.open...n/vavai/riv/zamer
issn
  • 0304-3894
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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