About: Effect of silver doping on the structure and phase separation of sulfur-rich As-S glasses: Raman and SEM studies

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	We report on the structural details and microphase separation of the bulk glasses Ag-x center dot (AS(33)S(67))(100-x) for 0<=x<=25. Class-glass phase separation occurs over a wide range of Ag content, 4<=x<=20. An off-resonant polarized Raman spectroscopic study has been carried out to elucidate structural aspects at the short- and medium-range structural order of the glasses. Analysis of Raman spectra revealed quantitative changes of the sulfur-rich microenvironments that reduce upon adding Ag. Scanning electron microscopy combined with X-rays microanalysis have been utilized to examine the type and extent of phase separation, and to provide quantitative details on the atomic concentrations in the Ag-poor and Ag-rich phases. We report on the structural details and microphase separation of the bulk glasses Ag-x center dot (AS(33)S(67))(100-x) for 0<=x<=25. Class-glass phase separation occurs over a wide range of Ag content, 4<=x<=20. An off-resonant polarized Raman spectroscopic study has been carried out to elucidate structural aspects at the short- and medium-range structural order of the glasses. Analysis of Raman spectra revealed quantitative changes of the sulfur-rich microenvironments that reduce upon adding Ag. Scanning electron microscopy combined with X-rays microanalysis have been utilized to examine the type and extent of phase separation, and to provide quantitative details on the atomic concentrations in the Ag-poor and Ag-rich phases. (en)
Title	Effect of silver doping on the structure and phase separation of sulfur-rich As-S glasses: Raman and SEM studies Effect of silver doping on the structure and phase separation of sulfur-rich As-S glasses: Raman and SEM studies (en)
skos:prefLabel	Effect of silver doping on the structure and phase separation of sulfur-rich As-S glasses: Raman and SEM studies Effect of silver doping on the structure and phase separation of sulfur-rich As-S glasses: Raman and SEM studies (en)
skos:notation	RIV/00216275:25310/09:00008353!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(LC523), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	37-42
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Wágner, Tomáš Frumar, Miloslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	312257
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/09:00008353
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Raman scattering; Fast ion conduction; Chalcogenides; Scanning electron microscopy; Phases and equilibria; Medium-range order; Short-range order; Calorimetry; Glass transition (en)
http://linked.open.../riv/klicoveSlovo	Short-range order Raman scattering Glass transition Chalcogenides Scanning electron microscopy Calorimetry Fast ion conduction Medium-range order Phases and equilibria
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[EA174A6F9665]
http://linked.open...i/riv/nazevZdroje	Journal of Non-Crystalline Solids
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	355
http://linked.open...iv/tvurceVysledku	Frumar, Miloslav Wágner, Tomáš Dracopoulos, V. Chrissanthopoulos, A. Yannopoulos, S. N. Krbal, M. Kyriazis, F.
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0022-3093
number of pages	5 (xsd:int)
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Effect of silver doping on the structure and phase separation of sulfur-rich As-S glasses: Raman and SEM studies Effect of silver doping on the structure and phase separation of sulfur-rich As-S glasses: Raman and SEM studies Effect of silver doping on the structure and phase separation of sulfur-rich As-S glasses: Raman and SEM studies Effect of silver doping on the structure and phase separation of sulfur-rich As-S glasses: Raman and SEM studies

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