About: Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O]: An N -> Sn Coordinated Stannonic Acid     Goto   Sponge   NotDistinct   Permalink

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Description
  • The discovery of the possible hydrolytic mechanism of the monoorganotin(IV) compound RSn(H2O)(O2CCF3)3 (2) resulted in the preparation of the first intramolecularly coordinated stannonic acid, [RSn(OH)O]6 (3) (R is the N,C,N-pincer ligand [2,6-(Me2NCH2)2C6H3]-). The presence of N-Sn coordination prevents the formation of additional Sn-O interactions and results in the stabilization of the unique centrosymmetric {Sn6O12} core in 3.
  • The discovery of the possible hydrolytic mechanism of the monoorganotin(IV) compound RSn(H2O)(O2CCF3)3 (2) resulted in the preparation of the first intramolecularly coordinated stannonic acid, [RSn(OH)O]6 (3) (R is the N,C,N-pincer ligand [2,6-(Me2NCH2)2C6H3]-). The presence of N-Sn coordination prevents the formation of additional Sn-O interactions and results in the stabilization of the unique centrosymmetric {Sn6O12} core in 3. (en)
Title
  • Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O]: An N -> Sn Coordinated Stannonic Acid
  • Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O]: An N -> Sn Coordinated Stannonic Acid (en)
skos:prefLabel
  • Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O]: An N -> Sn Coordinated Stannonic Acid
  • Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O]: An N -> Sn Coordinated Stannonic Acid (en)
skos:notation
  • RIV/00216275:25310/09:00008339!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/07/0468), P(LC523), Z(MSM0021627501), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika
  • 15
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 345128
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/09:00008339
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • organotin; chelating ligand; X ray analysis (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [FC140AD2B8D2]
http://linked.open...i/riv/nazevZdroje
  • Organometallics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 28
http://linked.open...iv/tvurceVysledku
  • Dostál, Libor
  • Jambor, Roman
  • Růžička, Aleš
  • Jirásko, Robert
  • Bouška, Marek
http://linked.open...n/vavai/riv/zamer
issn
  • 0276-7333
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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