About: Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The reactions of the dimeric organoantimony(III) oxide containing the NCN chelating ligand L, with the trifluoroacetic and the trifluoromethanesulfonic acid gave unprecedented organoantimony hydroxides LSb(OH)(X) (X = triflate or trifluoroacetate). On the other hand, analogous reaction with the acetic acid and the tetrafluroboric acid led to a polar group exchange. By an analogy, the reaction of the organobismuth oxide gave the bismuth acetate in the reaction with the acetic acid, but the hydroxide LBi(OH)(triflate) was obtained, when the trifluoromethanesulfonic acid was used. The reactions of the dimeric organoantimony(III) oxide containing the NCN chelating ligand L, with the trifluoroacetic and the trifluoromethanesulfonic acid gave unprecedented organoantimony hydroxides LSb(OH)(X) (X = triflate or trifluoroacetate). On the other hand, analogous reaction with the acetic acid and the tetrafluroboric acid led to a polar group exchange. By an analogy, the reaction of the organobismuth oxide gave the bismuth acetate in the reaction with the acetic acid, but the hydroxide LBi(OH)(triflate) was obtained, when the trifluoromethanesulfonic acid was used. (en)
Title	Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand (en)
skos:prefLabel	Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand (en)
skos:notation	RIV/00216275:25310/09:00008331!RIV10-MSM-25310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/0468), P(GP203/07/P094), P(LC523), Z(MSM0021627501), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika	18
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Erben, Milan Dostál, Libor Růžička, Aleš Jambor, Roman Jirásko, Robert
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	345083
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/09:00008331
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	antimony; bismuth; chelating ligand; hydrolysis; cations (en)
http://linked.open.../riv/klicoveSlovo	cations bismuth hydrolysis antimony chelating ligand
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[84958A7AC699]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Study of properties and the use of C,N- and Y,C,Y-chelated organometallic compounds Organoantimony(III) and organobismuth(III) compounds containing O,C,O chelating ligands
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	28
http://linked.open...iv/tvurceVysledku	Dostál, Libor Erben, Milan Jambor, Roman Padělková, Zdeňka Růžička, Aleš Svoboda, Tomáš Jirásko, Robert Fridrichová, Adéla
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures Pokročilé analytické a separační metody a jejich aplikace v diagnostice a technologii živých a neživých materiálů
issn	0276-7333
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand

Faceted Search & Find service v1.16.116 as of Feb 22 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3239 as of Feb 22 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 80 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software