About: Intramolecularly Coordinated Organotin(IV) Sulphides and Their Reaktivity to Iodine

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Organotin(IV) sulphides (LSnPhS)2 (3) and (LSnPh2)2S (4) containing O,C,O chelating ligand (L = 2,6-(t BuOCH2)2C6H3) were prepared by the reaction of parent organotin chlorides LSnPhCl2 (1) and LSnPh2Cl (2) with Na2S Æ 9H2O in toluene/water. Both sulphides were characterized by the help of elemental analysis, ESI-mass spectrometry, 1H, 13C 119Sn NMR spectroscopy and the molecular structure of 3 was determined by X-ray diffraction techniques. Compounds 3 and 4 react with I2 to organotin iodides LSnPhI2 (5) and LSnPh2I (6), instead of intended iodolysis of phenyl groups. Triorganotin iodide 6 reacts with the additional molecule of I2 forming an ionic organotin compound [ LSnPh2]+ I3 (7), which is unstable in solution and decomposes to Ph2SnI2 and 2,6-(tBuOCH2)2C6H3I (8). Organotin(IV) sulphides (LSnPhS)2 (3) and (LSnPh2)2S (4) containing O,C,O chelating ligand (L = 2,6-(t BuOCH2)2C6H3) were prepared by the reaction of parent organotin chlorides LSnPhCl2 (1) and LSnPh2Cl (2) with Na2S Æ 9H2O in toluene/water. Both sulphides were characterized by the help of elemental analysis, ESI-mass spectrometry, 1H, 13C 119Sn NMR spectroscopy and the molecular structure of 3 was determined by X-ray diffraction techniques. Compounds 3 and 4 react with I2 to organotin iodides LSnPhI2 (5) and LSnPh2I (6), instead of intended iodolysis of phenyl groups. Triorganotin iodide 6 reacts with the additional molecule of I2 forming an ionic organotin compound [ LSnPh2]+ I3 (7), which is unstable in solution and decomposes to Ph2SnI2 and 2,6-(tBuOCH2)2C6H3I (8). (en) byly připraveny organocíničité sulfidy obsahující YCY ligandy (cs)
Title	Intramolecularly Coordinated Organotin(IV) Sulphides and Their Reaktivity to Iodine Intramolecularly Coordinated Organotin(IV) Sulphides and Their Reaktivity to Iodine (en) Příprava a reaktivita organocíničitých sulfidů (cs)
skos:prefLabel	Intramolecularly Coordinated Organotin(IV) Sulphides and Their Reaktivity to Iodine Intramolecularly Coordinated Organotin(IV) Sulphides and Their Reaktivity to Iodine (en) Příprava a reaktivita organocíničitých sulfidů (cs)
skos:notation	RIV/00216275:25310/07:00005858!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany	3750-3757
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/0468), P(LC523), Z(MSM0021627501), Z(MSM0021627502)
http://linked.open...iv/cisloPeriodika	17
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Dostál, Libor Růžička, Aleš Jambor, Roman Jirásko, Robert Holeček, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Pardubice / Fakulta chemicko-technologická
http://linked.open...dnocenehoVysledku	427341
http://linked.open...ai/riv/idVysledku	RIV/00216275:25310/07:00005858
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	organotin; YCY ligand (en)
http://linked.open.../riv/klicoveSlovo	organotin YCY ligand
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[658EBA5E9A83]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Study of properties and the use of C,N- and Y,C,Y-chelated organometallic compounds
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	692
http://linked.open...iv/tvurceVysledku	Dostál, Libor Jambor, Roman Růžička, Aleš Jirásko, Robert Holeček, Jaroslav Taraba, Jan
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures Pokročilé analytické a separační metody a jejich aplikace v diagnostice a technologii živých a neživých materiálů
issn	0022-328X
number of pages	8 (xsd:int)
http://localhost/t...ganizacniJednotka	25310
is http://linked.open...avai/riv/vysledek of	Intramolecularly Coordinated Organotin(IV) Sulphides and Their Reaktivity to Iodine Intramolecularly Coordinated Organotin(IV) Sulphides and Their Reaktivity to Iodine Intramolecularly Coordinated Organotin(IV) Sulphides and Their Reaktivity to Iodine

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