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Description
  • Několik nových organometalických iniciátorů kationtově polymerujících UV barev bylo připraveno a jejich účinost byla sledována v porovnání s komerčním iniciátorem Irgacure 261. (cs)
  • A several new arene-iron complexes were prepared by the treatment of chlorobenzene with ferrocene in the presence of aluminium. The obtained chloroaluminate complexes were converted into hexafluorophosphates by treatment with aqueous solution of hexafluorophosphate salt. The hexafluorophosphate complexes are easier to store and handle. These compounds were characterized by NMR and MS spectroscopy. The UV light decomposes arene-ironcyclopentadienyl (arene-FeCp+) cation selectively to the corresponding aromatic compound and iron cyclopentadiene (CpFe+) cation. During irradiation formed FeCp+ is the active species for cationic polymerization. The polymerization activities of prepared arene-FeCp+ complexes for epoxide and vinylether monomers were measured by FTIR spectroscopy. The solubility of prepared compounds in the monomer is limited factor for application of these compounds.
  • A several new arene-iron complexes were prepared by the treatment of chlorobenzene with ferrocene in the presence of aluminium. The obtained chloroaluminate complexes were converted into hexafluorophosphates by treatment with aqueous solution of hexafluorophosphate salt. The hexafluorophosphate complexes are easier to store and handle. These compounds were characterized by NMR and MS spectroscopy. The UV light decomposes arene-ironcyclopentadienyl (arene-FeCp+) cation selectively to the corresponding aromatic compound and iron cyclopentadiene (CpFe+) cation. During irradiation formed FeCp+ is the active species for cationic polymerization. The polymerization activities of prepared arene-FeCp+ complexes for epoxide and vinylether monomers were measured by FTIR spectroscopy. The solubility of prepared compounds in the monomer is limited factor for application of these compounds. (en)
Title
  • Organometalic Cationic Initiators for UV Inks
  • Organometalic Cationic Initiators for UV Inks (en)
  • Organometalické kationtové iniciátory UV barev (cs)
skos:prefLabel
  • Organometalic Cationic Initiators for UV Inks
  • Organometalic Cationic Initiators for UV Inks (en)
  • Organometalické kationtové iniciátory UV barev (cs)
skos:notation
  • RIV/00216275:25310/06:00004660!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 142
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021627501)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 491034
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/06:00004660
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • photoinitiator; UV polymerization; cationic polymerization; FTIR; UV-VIS (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [1266ED8D7E9E]
http://linked.open...i/riv/mistoVydani
  • Ljubljana, Slovenia
http://linked.open...i/riv/nazevZdroje
  • Book of Abstracts (+ Conference Proceedings CD)
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Jašúrek, Bohumil
  • Vališ, Jan
  • Weidlich, Tomáš
  • Otáhalová, Lenka
  • Knobloch, Josef
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • University of Ljubljana
https://schema.org/isbn
  • 961-6045-35-0
http://localhost/t...ganizacniJednotka
  • 25310
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