About: Metallocene complexes for air drying organic coatings     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • Sikativa jsou aditiva přidáváná jako katalyzátory vytvrzení oxypolymeračně zasychajících organických povlaků. Kobalt oktoát byl nejrozšířenějším sikativem pro vynikající vlastností. Protože byla objevena karcinogenita a genotoxicita kobaltu a solí kobaltu, je nezbytné redukovat množství kobaltu v průmyslu nátěrových hmot. Práce se zabývá použitím ferocenu a jeho derivátů jako sikativů pro oxidačně zasychající povlaky. Byl uvažován synergický efekt mezi metalocenovými komlexy a kobatovým sikativem. V prvním kroku práce byla studována kinetika autooxidace pomocí FTIR. Dále byly metallocenové komplexy aplikovány do roztoku alkydové pryskyřice a měřen vliv na povrchovou tvrdost povlaků. (cs)
  • Driers are added to air drying paints to accelerate the hardening of spread coating. For decades cobalt octoate has been most widely used drier because of its good. Recently, several reports describing possible carcinogenity and genotoxicity of cobalt and cobalt salts, such as cobalt sulphate in aerosols, have appeared. It is necessary to reduce the amount of cobalt compounds in coatings industry. Present study deals with the possibility of using ferrocene and its derivatives as driers for air drying coatings. Were concentred particularly on the synergic effect between these metallocene complexes and the cobalt drier. In the first step there was investigated the kinetics of autooxidation by FTIR spectroscopy in model systems. Then the metallocene complexes were applied together with cobalt drier to alkyd resin, where was examined their influence on hardness of spread coatings.
  • Driers are added to air drying paints to accelerate the hardening of spread coating. For decades cobalt octoate has been most widely used drier because of its good. Recently, several reports describing possible carcinogenity and genotoxicity of cobalt and cobalt salts, such as cobalt sulphate in aerosols, have appeared. It is necessary to reduce the amount of cobalt compounds in coatings industry. Present study deals with the possibility of using ferrocene and its derivatives as driers for air drying coatings. Were concentred particularly on the synergic effect between these metallocene complexes and the cobalt drier. In the first step there was investigated the kinetics of autooxidation by FTIR spectroscopy in model systems. Then the metallocene complexes were applied together with cobalt drier to alkyd resin, where was examined their influence on hardness of spread coatings. (en)
Title
  • Metallocene complexes for air drying organic coatings
  • Metallocene complexes for air drying organic coatings (en)
  • Komlexy metalocenu pro oxidačně zasychající organické povlaky (cs)
skos:prefLabel
  • Metallocene complexes for air drying organic coatings
  • Metallocene complexes for air drying organic coatings (en)
  • Komlexy metalocenu pro oxidačně zasychající organické povlaky (cs)
skos:notation
  • RIV/00216275:25310/06:00004443!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 113-118
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 485040
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/06:00004443
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • driers; metallocene complexes; cobalt; autoxidation; organic coating (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • SK - Slovenská republika
http://linked.open...ontrolniKodProRIV
  • [4641710E2512]
http://linked.open...i/riv/nazevZdroje
  • Acta Mechanica Slovaca
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 10
http://linked.open...iv/tvurceVysledku
  • Erben, Milan
  • Kalenda, Petr
  • Veselý, David
  • Šťáva, Vít
http://linked.open...n/vavai/riv/zamer
issn
  • 1335-2393
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
is http://linked.open...avai/riv/vysledek of
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software