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Description
  • K analýze substitučních efektů na naftalenovém skeletu byly použita série hodnot disociačních konstant 45 substituovaných 1- a 2-naftoových kyselin změřených v šesti organických rozpouštědlech. Regresní analýza byla provedena podle rovnice Dewar-Grisdale, Taftovy rovnice a s využitím přístupu AISE - alternativní interpretace substitučních efektů. Data byla rovněž podrobena analýze hlavních komponent (PCA). Za účelem dalšího rozšíření analýzy byla ke zmiňovaných datům přidána literární data popisující reaktivitu příbuzných naftalenových derivátů. (cs)
  • The dissociation constants of 45 substituted 1- and 2-naphthoic acids in six organic solvents have been used to evaluate the substituent effects in the naphthalene skeleton. Dewar-Grisdale equation, Taft DSP equation and AISE method have been used for regression analysis. The principal component analysis (PCA) has been also applied. Reactivity data for other naphthalene derivatives taken from literature have been added to this analysis.
  • The dissociation constants of 45 substituted 1- and 2-naphthoic acids in six organic solvents have been used to evaluate the substituent effects in the naphthalene skeleton. Dewar-Grisdale equation, Taft DSP equation and AISE method have been used for regression analysis. The principal component analysis (PCA) has been also applied. Reactivity data for other naphthalene derivatives taken from literature have been added to this analysis. (en)
Title
  • Analýza substitučních efektů na naftalenu (cs)
  • Analysis of Substituent Effects in Naphthalene Skeleton
  • Analysis of Substituent Effects in Naphthalene Skeleton (en)
skos:prefLabel
  • Analýza substitučních efektů na naftalenu (cs)
  • Analysis of Substituent Effects in Naphthalene Skeleton
  • Analysis of Substituent Effects in Naphthalene Skeleton (en)
skos:notation
  • RIV/00216275:25310/04:00003438!RIV08-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 2297-2314
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 253100001)
http://linked.open...iv/cisloPeriodika
  • 12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 554277
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/04:00003438
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Naphthoic acids; Dissociation constants; Substituent effects; Solvent effects; Chemometrics; Naphthalenes; Carboxylic acids; Acidity; AISE (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [5457723C5EF8]
http://linked.open...i/riv/nazevZdroje
  • Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 69
http://linked.open...iv/tvurceVysledku
  • Ludwig, Miroslav
  • Pařík, Patrik
http://linked.open...n/vavai/riv/zamer
issn
  • 0010-0765
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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