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Description
  • Vliv příspěvku nelinearity na objemovou a entalpickou relaxaci amorfních materiálů byl analyzován s využitím Tool - Narayanaswamy - Moynihan modelu. Byla odvozena rovnice vyjadřující rychlost relaxace v závislosti na příspěvku nelinearity, šířky spektra relaxačních časů a velikosti teplotní změny. (cs)
  • The effect of non-linearity contribution to the relaxation behavior of amorphous materials is analyzed within the Tool-Narayanaswamy-Moynihan (TNM) model. It is shown that the rate of relaxation response to a temperature jump can conveniently be characterized on the basis of the stabilization period and the fictive relaxation rate. A simple equation relating these quantities and parameters of the TNM model is derived. This equation separates the contribution of non-exponentiality and non-linearity. It has been tested for polyvinylacetate and As2S3 relaxation data. Within the limits of experimental error it seems that volume and enthalpy relaxations in these materials exhibit a similar response that can be well correlated with previously published TNM parameters.
  • The effect of non-linearity contribution to the relaxation behavior of amorphous materials is analyzed within the Tool-Narayanaswamy-Moynihan (TNM) model. It is shown that the rate of relaxation response to a temperature jump can conveniently be characterized on the basis of the stabilization period and the fictive relaxation rate. A simple equation relating these quantities and parameters of the TNM model is derived. This equation separates the contribution of non-exponentiality and non-linearity. It has been tested for polyvinylacetate and As2S3 relaxation data. Within the limits of experimental error it seems that volume and enthalpy relaxations in these materials exhibit a similar response that can be well correlated with previously published TNM parameters. (en)
Title
  • The effect of non-linearity contribution to the volume and enthalpy relaxations in amorphous materials
  • The effect of non-linearity contribution to the volume and enthalpy relaxations in amorphous materials (en)
  • Vliv příspěvku nelinearity na objemovou a entalpickou relaxaci amorfních materiálů (cs)
skos:prefLabel
  • The effect of non-linearity contribution to the volume and enthalpy relaxations in amorphous materials
  • The effect of non-linearity contribution to the volume and enthalpy relaxations in amorphous materials (en)
  • Vliv příspěvku nelinearity na objemovou a entalpickou relaxaci amorfních materiálů (cs)
skos:notation
  • RIV/00216275:25310/02:00008248!RIV09-MSM-25310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LA 117)
http://linked.open...iv/cisloPeriodika
  • 307-310
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 644264
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/02:00008248
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Inorganic compounds; Theoretical study; Arsenic sulfides; Amorphous state; Volume; Non linear effect; Enthalpy; Structure relaxation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [265A89005A73]
http://linked.open...i/riv/nazevZdroje
  • Journal of Non-Crystalline Solids
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • N
http://linked.open...iv/tvurceVysledku
  • Málek, Jiří
  • Shánělová, Jana
issn
  • 0022-3093
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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