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Description
  • The applications of gold-plated carbon paste electrodes in anodic stripping voltammetry have been studied in an effort to develop a simple and effective method for the determination of arsenic in water samples. The investigations performed included the choice of supporting electrolyte composition, the optimisation of important experimental parameters, search for appropriate procedure to reduce As(V) to As(III), and some tests of practical applicability of the method, including interference studies. Under optimised conditions, the signal of As was linear within 5-50 mu g l(-1) with a detection limit of about 1 mu g l(-1) As (deposit ion time 10 min). Common elements or ions did not interfere except for Cu(II). The analytical performance of the method has been tested in recovery measurements with model solutions.
  • The applications of gold-plated carbon paste electrodes in anodic stripping voltammetry have been studied in an effort to develop a simple and effective method for the determination of arsenic in water samples. The investigations performed included the choice of supporting electrolyte composition, the optimisation of important experimental parameters, search for appropriate procedure to reduce As(V) to As(III), and some tests of practical applicability of the method, including interference studies. Under optimised conditions, the signal of As was linear within 5-50 mu g l(-1) with a detection limit of about 1 mu g l(-1) As (deposit ion time 10 min). Common elements or ions did not interfere except for Cu(II). The analytical performance of the method has been tested in recovery measurements with model solutions. (en)
  • Uhlíková pastová elektroda s vyloučeným zlatým filmem ke stanovení arsenu anodickou rozpouštěcí analýzou (cs)
Title
  • Gold-plated carbon paste electrodes for anodic stripping determination of arsenic
  • Gold-plated carbon paste electrodes for anodic stripping determination of arsenic (en)
  • Uhlíková pastová elektroda s vyloučeným zlatým filmem ke stanovení arsenu anodickou rozpouštěcí analýzou (cs)
skos:prefLabel
  • Gold-plated carbon paste electrodes for anodic stripping determination of arsenic
  • Gold-plated carbon paste electrodes for anodic stripping determination of arsenic (en)
  • Uhlíková pastová elektroda s vyloučeným zlatým filmem ke stanovení arsenu anodickou rozpouštěcí analýzou (cs)
skos:notation
  • RIV/00216275:25310/00:00003863!RIV06-MSM-25310___
http://linked.open.../vavai/riv/strany
  • 1035-1046
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/99/0044), P(OE37/1)
http://linked.open...iv/cisloPeriodika
  • 6
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 712104
http://linked.open...ai/riv/idVysledku
  • RIV/00216275:25310/00:00003863
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • gold film electrode; carbon paste support; arsenic(III); arsenic(V); stripping voltammetry; electroreductions; electrochemistry (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [69112894BFC7]
http://linked.open...i/riv/nazevZdroje
  • Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Vytřas, Karel
  • Švancara, Ivan
  • Chadim, P.
  • Pihlar, B.
issn
  • 0010-0765
number of pages
http://localhost/t...ganizacniJednotka
  • 25310
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