About: Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract
Description	High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules. High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules. (en)
Title	Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface (en)
skos:prefLabel	Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface (en)
skos:notation	RIV/00216224:14740/14:00076814!RIV15-MSM-14740___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(LD13060), P(LD14115)
http://linked.open...iv/cisloPeriodika	57
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Šponer, Jiří Šponer, Judit E.
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Středoevropský technologický institut
http://linked.open...dnocenehoVysledku	43274
http://linked.open...ai/riv/idVysledku	RIV/00216224:14740/14:00076814
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	TITANIUM-DIOXIDE; OXYGEN-EXCHANGE; CARBON-MONOXIDE; HYDROCARBONS; CHEMISTRY; TIO2(101); OXIDATION; ISOTOPE; METAL; FTIR (en)
http://linked.open.../riv/klicoveSlovo	TITANIUM-DIOXIDE CHEMISTRY HYDROCARBONS ISOTOPE OXYGEN-EXCHANGE TIO2(101) FTIR METAL OXIDATION CARBON-MONOXIDE
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[F3F52B64A2C8]
http://linked.open...i/riv/nazevZdroje	Chemical Communications
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Metal oxide nanoparticles and their reactivity studied by high resolution FT infrared spectroscopy Electrons injection into Ti(IV) based oxidic materials: Application in Li-ion batteries and solar cells.
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	50
http://linked.open...iv/tvurceVysledku	Civiš, Svatopluk Ferus, Martin Kavan, Ladislav Zukalová, Markéta Šponer, Jiří Šponerová, Judit
http://linked.open...ain/vavai/riv/wos	000338234000038
issn	1359-7345
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1039/c4cc01992j
http://localhost/t...ganizacniJednotka	14740

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