About: Role of O,C,O-ligand in a new coordination mode of organotin compounds to 2-mercapto-1-methylimidazol. Stabilization of its thione form     Goto   Sponge   NotDistinct   Permalink

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Description
  • The reaction of the organotin compound [Ph2LSn](+) [OTf](-) (1), (L(O,C,O) = 2,6-(t-BuOCH2)(2)C6H3), with the sodium salt Na(mimt), mimt = 1-methylimidazole-2-thiolate, resulted in the isolation of Ph2LSn(mimt) (2), where the polar group (mimt) has been stabilized as the thione-tautomeric form by the triorganotin fragment Ph2LSn. Product 2 was characterized by H-1, C-13 and Sn-119 NMR and IR spectroscopy, ESI/MS, elemental analyses and X-ray diffraction.
  • The reaction of the organotin compound [Ph2LSn](+) [OTf](-) (1), (L(O,C,O) = 2,6-(t-BuOCH2)(2)C6H3), with the sodium salt Na(mimt), mimt = 1-methylimidazole-2-thiolate, resulted in the isolation of Ph2LSn(mimt) (2), where the polar group (mimt) has been stabilized as the thione-tautomeric form by the triorganotin fragment Ph2LSn. Product 2 was characterized by H-1, C-13 and Sn-119 NMR and IR spectroscopy, ESI/MS, elemental analyses and X-ray diffraction. (en)
Title
  • Role of O,C,O-ligand in a new coordination mode of organotin compounds to 2-mercapto-1-methylimidazol. Stabilization of its thione form
  • Role of O,C,O-ligand in a new coordination mode of organotin compounds to 2-mercapto-1-methylimidazol. Stabilization of its thione form (en)
skos:prefLabel
  • Role of O,C,O-ligand in a new coordination mode of organotin compounds to 2-mercapto-1-methylimidazol. Stabilization of its thione form
  • Role of O,C,O-ligand in a new coordination mode of organotin compounds to 2-mercapto-1-methylimidazol. Stabilization of its thione form (en)
skos:notation
  • RIV/00216224:14330/07:00020186!RIV10-GA0-14330___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GP203/05/P104), Z(MSM 143100011)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 448214
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14330/07:00020186
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • OCO ligand coordination mode organotin compound stabilization thione form (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [F35C29FA9EC6]
http://linked.open...i/riv/nazevZdroje
  • Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 692/2007
http://linked.open...iv/tvurceVysledku
  • Jambor, Roman
  • Taraba, Jan
  • Dostal, Libor
  • Martincova, Jana
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-328X
number of pages
http://localhost/t...ganizacniJednotka
  • 14330
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