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Description
| - Several salts of bis(chlorosulfonyl)imide HN(SO2Cl)2 (1), namely two solvates of its potassium salt, KN(SO2Cl)2 1/2 CH3CN (1K1), KN(SO2Cl)2 1/6 CH2Cl2 (1K2), and tetrachlorophosphonium salt, [PCl4][N(SO2Cl)2] (2), were prepared and structurally characterized. The reaction of HN(SO2Cl)2 with Me3N gives the [N(SO2Cl)2]- salt of a novel cation, [N(SO2NMe3)2]+ .This cation is analogous to the [HC(SO2NMe3)2]+ cation but, in contrast to the latter, it is fairly stable to hydrolysis. The salt [N(SO2NMe3)2]+ [N(SO2Cl)2]- (3) can be converted into salts of other anions by its treatment with diluted aqueous solutions of the respective acids, and thus NO3-, Cl-.H2O, SeO32-, CH3COO-, HSO4-, (COO)22- salts were prepared. Treatment of 3 with concentrated HNO3 gave the [N(SO2NMe3)2]+ [O2NO-H-ONO2]- salt, and the addition of an HCl acidified FeCl3 aqueous solution yielded the FeCl4- salt. Methanolysis resulted in the formation of MeOSO3- and [MeOSO2NSO2OMe]- salts.
- Several salts of bis(chlorosulfonyl)imide HN(SO2Cl)2 (1), namely two solvates of its potassium salt, KN(SO2Cl)2 1/2 CH3CN (1K1), KN(SO2Cl)2 1/6 CH2Cl2 (1K2), and tetrachlorophosphonium salt, [PCl4][N(SO2Cl)2] (2), were prepared and structurally characterized. The reaction of HN(SO2Cl)2 with Me3N gives the [N(SO2Cl)2]- salt of a novel cation, [N(SO2NMe3)2]+ .This cation is analogous to the [HC(SO2NMe3)2]+ cation but, in contrast to the latter, it is fairly stable to hydrolysis. The salt [N(SO2NMe3)2]+ [N(SO2Cl)2]- (3) can be converted into salts of other anions by its treatment with diluted aqueous solutions of the respective acids, and thus NO3-, Cl-.H2O, SeO32-, CH3COO-, HSO4-, (COO)22- salts were prepared. Treatment of 3 with concentrated HNO3 gave the [N(SO2NMe3)2]+ [O2NO-H-ONO2]- salt, and the addition of an HCl acidified FeCl3 aqueous solution yielded the FeCl4- salt. Methanolysis resulted in the formation of MeOSO3- and [MeOSO2NSO2OMe]- salts. (en)
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Title
| - A Novel Cation [N(SO2NMe3)2]+, its Synthesis and Crystal Structure. Dichloride of Imido-bis(sulfuric) Acid HN(SO2Cl)2. Part I. Crystal Structures of KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 and [PCl4][N(SO2Cl)2].
- A Novel Cation [N(SO2NMe3)2]+, its Synthesis and Crystal Structure. Dichloride of Imido-bis(sulfuric) Acid HN(SO2Cl)2. Part I. Crystal Structures of KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 and [PCl4][N(SO2Cl)2]. (en)
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skos:prefLabel
| - A Novel Cation [N(SO2NMe3)2]+, its Synthesis and Crystal Structure. Dichloride of Imido-bis(sulfuric) Acid HN(SO2Cl)2. Part I. Crystal Structures of KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 and [PCl4][N(SO2Cl)2].
- A Novel Cation [N(SO2NMe3)2]+, its Synthesis and Crystal Structure. Dichloride of Imido-bis(sulfuric) Acid HN(SO2Cl)2. Part I. Crystal Structures of KN(SO2Cl)2 1/2 CH3CN, KN(SO2Cl)2 1/6 CH2Cl2 and [PCl4][N(SO2Cl)2]. (en)
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skos:notation
| - RIV/00216224:14330/06:00015666!RIV10-GA0-14330___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GP203/05/P104), Z(MSM 143100011)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216224:14330/06:00015666
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Novel Cation; Synthesis; Imido-bis(sulfuric) Acid; Crystal Structures (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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is http://linked.open...avai/riv/vysledek
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