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Description
  • The reaction of Cu(PPh3)2NO3 with K[Ph2P(Se)-N-P(Se)Ph2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent gave with Co(PPh3)2Cl2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph2]2, containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-Ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations.
  • The reaction of Cu(PPh3)2NO3 with K[Ph2P(Se)-N-P(Se)Ph2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent gave with Co(PPh3)2Cl2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph2]2, containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-Ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations. (en)
  • The reaction of Cu(PPh3)2NO3 with K[Ph2P(Se)-N-P(Se)Ph2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent gave with Co(PPh3)2Cl2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph2]2, containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-Ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations. (cs)
Title
  • Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles
  • Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles (en)
  • Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles (cs)
skos:prefLabel
  • Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles
  • Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles (en)
  • Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray cryst. structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorg. metallocycles (cs)
skos:notation
  • RIV/00216224:14310/99:00001110!RIV09-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 143100011)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 738754
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/99:00001110
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • crystal structures; copper complexes; diselenoimidodiphosphinato complexes (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [0E2FCA1D1C00]
http://linked.open...i/riv/nazevZdroje
  • Inorganica Chimica Acta
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 290
http://linked.open...iv/tvurceVysledku
  • Marek, Jaromír
  • Nečas, Marek
  • Novosad, Josef
  • Papadimitriou, Christos
  • Haiduc, Ionel
  • Veltsistas, Panagiotis
  • Watanabe, Makoto
  • Woollins, Derek J.
http://linked.open...ain/vavai/riv/wos
  • 000081407600018
http://linked.open...n/vavai/riv/zamer
issn
  • 0020-1693
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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