About: X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands

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About: X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The detailed X-ray structural elucidation of reaction products of a zinc(II) salt with O,O-dialkyldithiophosphate and nitrogen-containing heterocycles (N–N=1,10-phenanthroline (phen) or 2,2-bipyridine (bpy)) has been performed. Surprisingly, together with [Zn(S2P(OR)2)2(N–N)] compounds, also ionic-type complexes having the formula of [Zn(N–N)3](S2 P(OR)2)2 have been obtained using the same molar ratios of the reactants. The prepared complexes have been characterized by elemental analysis and single-crystal X-ray analysis. The crystallographic analysis showed that the bond lengths and bite angles of the prepared complexes are in good agreement with those of similar compounds. The crystal packing of described complexes is formed via pi–pi stacking interactions and/or C–HxxxS non-covalent contacts The detailed X-ray structural elucidation of reaction products of a zinc(II) salt with O,O-dialkyldithiophosphate and nitrogen-containing heterocycles (N–N=1,10-phenanthroline (phen) or 2,2-bipyridine (bpy)) has been performed. Surprisingly, together with [Zn(S2P(OR)2)2(N–N)] compounds, also ionic-type complexes having the formula of [Zn(N–N)3](S2 P(OR)2)2 have been obtained using the same molar ratios of the reactants. The prepared complexes have been characterized by elemental analysis and single-crystal X-ray analysis. The crystallographic analysis showed that the bond lengths and bite angles of the prepared complexes are in good agreement with those of similar compounds. The crystal packing of described complexes is formed via pi–pi stacking interactions and/or C–HxxxS non-covalent contacts (en)
Title	X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands (en)
skos:prefLabel	X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands (en)
skos:notation	RIV/00216224:14310/14:00075889!RIV15-MSM-14310___
http://linked.open...avai/riv/aktivita	S
http://linked.open...avai/riv/aktivity	S
http://linked.open...iv/cisloPeriodika	7
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Jeremias, Lukáš Novosad, Josef Demo, Gabriel Vícha, Jan Babiak, Michal
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	56471
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/14:00075889
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	1 1-dithiolate dithiophosphate zinc(II) complexes crystal structure analysis X-ray diffraction (en)
http://linked.open.../riv/klicoveSlovo	1 1-dithiolate dithiophosphate zinc(II) complexes crystal structure analysis X-ray diffraction
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[DC7A0FB35E5D]
http://linked.open...i/riv/nazevZdroje	Zeitschrift für Kristallographie - Crystalline Materials
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	229
http://linked.open...iv/tvurceVysledku	Demo, Gabriel Trávníček, Zdeněk Vícha, Jan Novosad, Josef Jeremias, Lukáš Babiak, Michal
http://linked.open...ain/vavai/riv/wos	000340864000007
issn	0044-2968
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1515/zkri-2014-1736
http://localhost/t...ganizacniJednotka	14310

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