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  • In this paper, possibilities and limits of the application of REE3+ luminescence (especially the Nd3+ F-4(3/2) -> I-4(9/2) emission) as structural probe are evaluated. Important factors controlling the Nd3+ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO4), xenotime-(Y) (YPO4),monazite-(Ce)(CePO4) and their synthetic analogues. Based on these examples we review in short that (1) REE3+ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE3+-related emission bands are a strong indicator for structural disorder.
  • In this paper, possibilities and limits of the application of REE3+ luminescence (especially the Nd3+ F-4(3/2) -> I-4(9/2) emission) as structural probe are evaluated. Important factors controlling the Nd3+ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO4), xenotime-(Y) (YPO4),monazite-(Ce)(CePO4) and their synthetic analogues. Based on these examples we review in short that (1) REE3+ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE3+-related emission bands are a strong indicator for structural disorder. (en)
Title
  • Factors affecting the Nd3+ (REE3+) luminescence of minerals
  • Factors affecting the Nd3+ (REE3+) luminescence of minerals (en)
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  • Factors affecting the Nd3+ (REE3+) luminescence of minerals
  • Factors affecting the Nd3+ (REE3+) luminescence of minerals (en)
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  • RIV/00216224:14310/13:00072835!RIV14-MSM-14310___
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  • P(EE2.3.20.0052)
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  • 3
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  • 74535
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  • RIV/00216224:14310/13:00072835
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  • RARE-EARTH ELEMENTS; SITE-SELECTIVE SPECTROSCOPY; RESOLUTION SPECTROMETRIC ANALYSIS; BACKSCATTERED ELECTRON IMAGES; CATHODOLUMINESCENCE CL; ACTIVATED CATHODOLUMINESCENCE; CRYSTAL-CHEMISTRY; HIGH-TEMPERATURE; SOLID-SOLUTIONS; MONAZITE (en)
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  • AT - Rakouská republika
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  • [A130A6718476]
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  • Mineralogy and Petrology
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  • 107
http://linked.open...iv/tvurceVysledku
  • Škoda, Radek
  • Talla, Dominik
  • Nasdala, Lutz
  • Ruschel, Katja
  • Goetze, Jens
  • Lenz, Christoph
http://linked.open...ain/vavai/riv/wos
  • 000321918700006
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  • 0930-0708
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  • 10.1007/s00710-013-0286-2
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  • 14310
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