About: Crystal structure, thermodynamic properties, and paragenesis of bukovskyite, Fe-2(AsO4)(SO4)(OH)center dot 9H(2)O     Goto   Sponge   NotDistinct   Permalink

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  • Bukovskyite is a relatively rare secondary ferric arsenate-sulfate. At the type locality near the municipality of Kutna Hora (Czech Republic), it is the main secondary mineral in the medieval dumps, where it occurs in enormous amounts and forms nodules of prodigious dimensions. We investigated the mineral bukovskyite and the type locality in detail to understand the abundance of the mineral at this locality. The crystal structure of bukovskyite was solved for bukovskyite crystals from Grossvoigtsberg (Germany) and found to be of the space group P (I) over bar with a final R factor of 5.08% from 2403 reflections. The lattice parameters at room temperature are a = 7.549(1) angstrom, b = 10.305(1) angstrom, c = 10.914(2) angstrom, alpha = 115.136(3)degrees, beta = 99.798(3)degrees, and gamma = 92.864(3)degrees. The structure consists of octahedral-tetrahedral Fe-arsenate chains. Sulfate tetrahedra are bonded to the chains and free H2O molecules via a complicated network of hydrogen bonds.
  • Bukovskyite is a relatively rare secondary ferric arsenate-sulfate. At the type locality near the municipality of Kutna Hora (Czech Republic), it is the main secondary mineral in the medieval dumps, where it occurs in enormous amounts and forms nodules of prodigious dimensions. We investigated the mineral bukovskyite and the type locality in detail to understand the abundance of the mineral at this locality. The crystal structure of bukovskyite was solved for bukovskyite crystals from Grossvoigtsberg (Germany) and found to be of the space group P (I) over bar with a final R factor of 5.08% from 2403 reflections. The lattice parameters at room temperature are a = 7.549(1) angstrom, b = 10.305(1) angstrom, c = 10.914(2) angstrom, alpha = 115.136(3)degrees, beta = 99.798(3)degrees, and gamma = 92.864(3)degrees. The structure consists of octahedral-tetrahedral Fe-arsenate chains. Sulfate tetrahedra are bonded to the chains and free H2O molecules via a complicated network of hydrogen bonds. (en)
Title
  • Crystal structure, thermodynamic properties, and paragenesis of bukovskyite, Fe-2(AsO4)(SO4)(OH)center dot 9H(2)O
  • Crystal structure, thermodynamic properties, and paragenesis of bukovskyite, Fe-2(AsO4)(SO4)(OH)center dot 9H(2)O (en)
skos:prefLabel
  • Crystal structure, thermodynamic properties, and paragenesis of bukovskyite, Fe-2(AsO4)(SO4)(OH)center dot 9H(2)O
  • Crystal structure, thermodynamic properties, and paragenesis of bukovskyite, Fe-2(AsO4)(SO4)(OH)center dot 9H(2)O (en)
skos:notation
  • RIV/00216224:14310/12:00064415!RIV13-MSM-14310___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • S, Z(MSM0021622412)
http://linked.open...iv/cisloPeriodika
  • 3
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  • 129131
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  • RIV/00216224:14310/12:00064415
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  • Bukovskyite; Crystal structure; Thermodynamics; Paragenesis (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • JP - Japonsko
http://linked.open...ontrolniKodProRIV
  • [5349AC9F98FC]
http://linked.open...i/riv/nazevZdroje
  • JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 107
http://linked.open...iv/tvurceVysledku
  • Loun, Jan
  • Novák, Milan
  • Plášil, Jakub
  • Škoda, Radek
  • Armbruster, Thomas
  • Fisher, Robert Allan
  • Johnson, Michel B
  • Lazic, Biljana
  • Majzlan, Juraj
  • White, Mary Anne
http://linked.open...ain/vavai/riv/wos
  • 000306347700003
http://linked.open...n/vavai/riv/zamer
issn
  • 1345-6296
number of pages
http://bibframe.org/vocab/doi
  • 10.2465/jmps.110930
http://localhost/t...ganizacniJednotka
  • 14310
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