About: The Study Of Monochlorinated Phenols Using Hyphenated Electrochemical Method

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://ehis.ebscohost.com/eds/pdfviewer/pdfviewer?sid=ecfa705b-755b-4e3e-9a17-35963da2f315%40sessionmgr113&vid=2&hid=102
Description	Cyclic voltammetric (CV) study of electrooxidation of monochlorophenols (2-chlorophenol, 3-chlorophenol, 4-chlorophenol) on a Pt electrode in 0.5 M H(2)SO(4) was combined with the experiment using electrochemical quartz crystal microbalance (EQCM). For all chlorophenols the polymeric film formation on the electrode surface has been observed and the electrode surface was completely covered with polymeric film after five cycles. Partial deactivation of the electrode resulting in the formation of the more permeable film was created in the case of 2-chlorophenol and the film of 4-chlorophenol was created also with the low permeability. The influence of the scan rate on the electrooxidation of chlorophenol was evaluated. It was found that the lower electropolymerization rate and better permeability of the film was observed at higher scan rates. Valuable insights into complex electrooxidation processes of all chlorophenols were also gained by means of the elimination voltammetry with linear scan (EVLS). Cyclic voltammetric (CV) study of electrooxidation of monochlorophenols (2-chlorophenol, 3-chlorophenol, 4-chlorophenol) on a Pt electrode in 0.5 M H(2)SO(4) was combined with the experiment using electrochemical quartz crystal microbalance (EQCM). For all chlorophenols the polymeric film formation on the electrode surface has been observed and the electrode surface was completely covered with polymeric film after five cycles. Partial deactivation of the electrode resulting in the formation of the more permeable film was created in the case of 2-chlorophenol and the film of 4-chlorophenol was created also with the low permeability. The influence of the scan rate on the electrooxidation of chlorophenol was evaluated. It was found that the lower electropolymerization rate and better permeability of the film was observed at higher scan rates. Valuable insights into complex electrooxidation processes of all chlorophenols were also gained by means of the elimination voltammetry with linear scan (EVLS). (en)
Title	The Study Of Monochlorinated Phenols Using Hyphenated Electrochemical Method The Study Of Monochlorinated Phenols Using Hyphenated Electrochemical Method (en)
skos:prefLabel	The Study Of Monochlorinated Phenols Using Hyphenated Electrochemical Method The Study Of Monochlorinated Phenols Using Hyphenated Electrochemical Method (en)
skos:notation	RIV/00216224:14310/11:00054983!RIV12-MSM-14310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(LC06035), S, Z(MSM0021622412)
http://linked.open...iv/cisloPeriodika	8
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Trnková, Libuše Roziková, Matilda
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	233087
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/11:00054983
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Chlorophenols electrooxidation; Cyclic voltammetry; Electrochemical quartz crystal microbalance (EQCM); Elimination voltammetry with linear scan (EVLS); Pt electrode; Electrochemistry; Elimination; Chlorophenols (en)
http://linked.open.../riv/klicoveSlovo	Electrochemistry Chlorophenols Chlorophenols electrooxidation Electrochemical quartz crystal microbalance (EQCM) Elimination Elimination voltammetry with linear scan (EVLS) Pt electrode Cyclic voltammetry
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[9582C6928AFF]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak chemical communications
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine.
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	76
http://linked.open...iv/tvurceVysledku	Trnková, Libuše Janderka, Pavel Roziková, Matilda
http://linked.open...n/vavai/riv/zamer	Interactions among the chemicals, environment and biological systems and their consequences on the global, regional and local scales (INCHEMBIOL)
issn	0010-0765
number of pages	15 (xsd:int)
http://bibframe.org/vocab/doi	10.1135/cccc2011062
http://localhost/t...ganizacniJednotka	14310
is http://linked.open...avai/riv/vysledek of	The Study Of Monochlorinated Phenols Using Hyphenated Electrochemical Method The Study Of Monochlorinated Phenols Using Hyphenated Electrochemical Method

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