About: Luminescent properties of europium complexes with bis(diphenylphosphino)alkane dioxides

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Eu(NO3)3.5H2O and EuCl3.6H2O were allowed to react with bis(diphenylphosphino)alkane dioxides Ph2P(O)(CH2)nP(O)Ph2 (n?=?2, 4, 6) to obtain polymeric and binuclear complexes. The prepared compounds were structurally characterized by X-ray diffraction. Luminescence measurements (emission and excitation spectra, quantum yields, lifetimes) were compared with crystallographic data in order to find a relationship between luminescent properties of the Eu(III) complexes and their structures. The Eu(III) polymers, especially {[Eu(dpphO2)2Cl2]+Cl-}n, have shown extremely long luminescence lifetimes, up to 3.73ms, as a result of a highly protecting hydrophobic shield. Eu(NO3)3.5H2O and EuCl3.6H2O were allowed to react with bis(diphenylphosphino)alkane dioxides Ph2P(O)(CH2)nP(O)Ph2 (n?=?2, 4, 6) to obtain polymeric and binuclear complexes. The prepared compounds were structurally characterized by X-ray diffraction. Luminescence measurements (emission and excitation spectra, quantum yields, lifetimes) were compared with crystallographic data in order to find a relationship between luminescent properties of the Eu(III) complexes and their structures. The Eu(III) polymers, especially {[Eu(dpphO2)2Cl2]+Cl-}n, have shown extremely long luminescence lifetimes, up to 3.73ms, as a result of a highly protecting hydrophobic shield. (en)
Title	Luminescent properties of europium complexes with bis(diphenylphosphino)alkane dioxides Luminescent properties of europium complexes with bis(diphenylphosphino)alkane dioxides (en)
skos:prefLabel	Luminescent properties of europium complexes with bis(diphenylphosphino)alkane dioxides Luminescent properties of europium complexes with bis(diphenylphosphino)alkane dioxides (en)
skos:notation	RIV/00216224:14310/11:00050235!RIV12-GA0-14310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	P S
http://linked.open...avai/riv/aktivity	P(GA203/08/1111), P(GP203/08/P325), S
http://linked.open...iv/cisloPeriodika	6
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Nečas, Marek Táborský, Petr Pekárková, Pavla Spíchal, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	210086
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/11:00050235
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	europium; coordination polymers; luminescence; diphosphine dioxides; crystal structures (en)
http://linked.open.../riv/klicoveSlovo	europium coordination polymers crystal structures diphosphine dioxides luminescence
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[45AA74024AAC]
http://linked.open...i/riv/nazevZdroje	Luminescence
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Synthesis and properties of inorganic-organic polymeric materials Preparation and study on properties of a new inorganic luminophores containing copper(I)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	26
http://linked.open...iv/tvurceVysledku	Nečas, Marek Táborský, Petr Pekárková, Pavla Spíchal, Zdeněk
issn	1522-7235
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/bio.1291
http://localhost/t...ganizacniJednotka	14310
is http://linked.open...avai/riv/vysledek of	Luminescent properties of europium complexes with bis(diphenylphosphino)alkane dioxides Luminescent properties of europium complexes with bis(diphenylphosphino)alkane dioxides

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