About: ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The electrode processes of chlorobenzene (CB) and fluorobenzene (FB) on polycrystalline platinum (Pt pc) electrode in sulfuric acid were studied by differential electrochemical mass spectrometry (DEMS). Contrary to the oxidation of adsorbed benzene on Pt surface, the oxidation of adsorbed CB and FB in the oxygen adsorption region does not provide solely CO2 as the final product. At negative polarization potentials CB and FB were desorbed under dehalogenation. While in the case of FB only benzene was detected, CB gave intermediates besides benzene. The final product of stepwise hydrogenation of these species was cyclohexane. The electrode processes of chlorobenzene (CB) and fluorobenzene (FB) on polycrystalline platinum (Pt pc) electrode in sulfuric acid were studied by differential electrochemical mass spectrometry (DEMS). Contrary to the oxidation of adsorbed benzene on Pt surface, the oxidation of adsorbed CB and FB in the oxygen adsorption region does not provide solely CO2 as the final product. At negative polarization potentials CB and FB were desorbed under dehalogenation. While in the case of FB only benzene was detected, CB gave intermediates besides benzene. The final product of stepwise hydrogenation of these species was cyclohexane. (en)
Title	ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE (en)
skos:prefLabel	ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE (en)
skos:notation	RIV/00216224:14310/09:00035344!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(OC 174), Z(AV0Z40500505), Z(MSM0021622412)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Kebrlová, Natálie Janderka, Pavel Trnková, Libuše
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	312816
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/09:00035344
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Electrochemical degradation; Hydrogenation; Dehalogenation; Fluorobenzene; Chlorobenzene; Differential electrochemical mass spectrometry (DEMS); Cyclic voltammetry (CV) (en)
http://linked.open.../riv/klicoveSlovo	Hydrogenation Dehalogenation Chlorobenzene Cyclic voltammetry (CV) Differential electrochemical mass spectrometry (DEMS) Electrochemical degradation Fluorobenzene
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[71F3D59734FB]
http://linked.open...i/riv/nazevZdroje	Collect. Czech. Chem. Commun.
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20174
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	74
http://linked.open...iv/tvurceVysledku	Trnková, Libuše Janderka, Pavel Kebrlová, Natálie
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie Interactions among the chemicals, environment and biological systems and their consequences on the global, regional and local scales (INCHEMBIOL)
issn	0010-0765
number of pages	14 (xsd:int)
http://localhost/t...ganizacniJednotka	14310
is http://linked.open...avai/riv/vysledek of	ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE ELECTROCHEMICAL PROCESSES OF ADSORBED CHLOROBENZENE AND FLUOROBENZENE ON A PLATINUM POLYCRYSTALLINE ELECTRODE

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