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rdf:type
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Description
| - The compounds [{VO(O-2)(2)(NH3)}(2){mu-Cu(NH3)(4)}] (1) and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (2) were prepared and characterized by elemental analysis and infrared spectra. The single crystal X-ray study revealed that the structure of 1 consists of trinuclear complex molecules [(NH3)OV(O-2)(2){mu-Cu(NH3)(4)}(O-2)(2)VO(NH3)] with a rare heterobimetalic peroxo bridge: copper(II)-peroxo ligand-vanadium(V). The structure of 2 is composed of tetraamminezinc(II) cations and ammineoxodiperoxovanadate(V) anions. In course of thermal decomposition of 1 performed up to 620 degrees C, the following intermediate products: [Cu(NH3)(2)(VO3)(2)], and subsequently a mixture of V2O5 with monoclinic beta-Cu2V2O7, were gradually formed. The final product of decomposition is Cu(Vo(3))(2). The thermal decomposition of 2 is a two-step process.
- The compounds [{VO(O-2)(2)(NH3)}(2){mu-Cu(NH3)(4)}] (1) and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (2) were prepared and characterized by elemental analysis and infrared spectra. The single crystal X-ray study revealed that the structure of 1 consists of trinuclear complex molecules [(NH3)OV(O-2)(2){mu-Cu(NH3)(4)}(O-2)(2)VO(NH3)] with a rare heterobimetalic peroxo bridge: copper(II)-peroxo ligand-vanadium(V). The structure of 2 is composed of tetraamminezinc(II) cations and ammineoxodiperoxovanadate(V) anions. In course of thermal decomposition of 1 performed up to 620 degrees C, the following intermediate products: [Cu(NH3)(2)(VO3)(2)], and subsequently a mixture of V2O5 with monoclinic beta-Cu2V2O7, were gradually formed. The final product of decomposition is Cu(Vo(3))(2). The thermal decomposition of 2 is a two-step process. (en)
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Title
| - Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2)
- Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (en)
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skos:prefLabel
| - Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2)
- Synthesis, X-ray crystal structure and thermal decomposition of two peroxovanadium complexes with coordinated ammonia molecules: [{VO(O-2)2(NH3)}(2){[mu-Cu(NH3)(4)}] and [Zn(NH3)(4)][VO(O-2)(2)(NH3)](2) (en)
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skos:notation
| - RIV/00216224:14310/08:00026161!RIV10-MSM-14310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00216224:14310/08:00026161
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - peroxovanadium complexes; ammine complexes; X-ray structure; IR spectra; thermal decomposition (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Marek, Jaromír
- Tatiersky, J.
- Schwendt, P.
- Chrappová, J.
- Dudášová, D.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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is http://linked.open...avai/riv/vysledek
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