About: Copper(II) complexes of tridentate selenobisphenolate ligand in mixed ligand environments: Synthesis, crystal structure, EPR and electrochemical studies

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A series of square-pyramidal copper(II) complexes, [Cu(L-Se)(N-N)] (H2LSe = seleno-bisphenolate; N-N = bipyridyl, phenanthroline or N,N-dimethylethylenediamine) have been synthesized and characterized by elemental analyses, magnetic measurements, IR, EPR, and electronic spectral studies. Single crystal X-ray structures of [Cu(L-Se)(bpy)]. H2O (2), [Cu(L-Se)(phen)]. CH2Cl2 (3) and [Cu(L-Se)(N,N-Me(2)en)] (4) showed that all the complexes have approximately square-pyramidal geometry. In complexes 2 and 3, the square plane is occupied by O(1) O(2) N(1) and N(2) and the apical position by Se atom of L(Se 2-)ligand. The asymmetric unit of complex 4 contains two crystallographically independent discrete molecules A and B with CuN2OSe chromophore comprising the square plane and the axial position being occupied by another phenolate oxygen atom. Complexes 2, 3 and 4 are found to be paramagnetic. A series of square-pyramidal copper(II) complexes, [Cu(L-Se)(N-N)] (H2LSe = seleno-bisphenolate; N-N = bipyridyl, phenanthroline or N,N-dimethylethylenediamine) have been synthesized and characterized by elemental analyses, magnetic measurements, IR, EPR, and electronic spectral studies. Single crystal X-ray structures of [Cu(L-Se)(bpy)]. H2O (2), [Cu(L-Se)(phen)]. CH2Cl2 (3) and [Cu(L-Se)(N,N-Me(2)en)] (4) showed that all the complexes have approximately square-pyramidal geometry. In complexes 2 and 3, the square plane is occupied by O(1) O(2) N(1) and N(2) and the apical position by Se atom of L(Se 2-)ligand. The asymmetric unit of complex 4 contains two crystallographically independent discrete molecules A and B with CuN2OSe chromophore comprising the square plane and the axial position being occupied by another phenolate oxygen atom. Complexes 2, 3 and 4 are found to be paramagnetic. (en)
Title	Copper(II) complexes of tridentate selenobisphenolate ligand in mixed ligand environments: Synthesis, crystal structure, EPR and electrochemical studies Copper(II) complexes of tridentate selenobisphenolate ligand in mixed ligand environments: Synthesis, crystal structure, EPR and electrochemical studies (en)
skos:prefLabel	Copper(II) complexes of tridentate selenobisphenolate ligand in mixed ligand environments: Synthesis, crystal structure, EPR and electrochemical studies Copper(II) complexes of tridentate selenobisphenolate ligand in mixed ligand environments: Synthesis, crystal structure, EPR and electrochemical studies (en)
skos:notation	RIV/00216224:14310/07:00022011!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM0021622410)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Marek, Jaromír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	415095
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/07:00022011
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	copper(II) complexes; mixed ligand environment; square-pyramidal structures; cyclic voltammetric studies (en)
http://linked.open.../riv/klicoveSlovo	cyclic voltammetric studies mixed ligand environment square-pyramidal structures copper(II) complexes
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[87AEA4BB1702]
http://linked.open...i/riv/nazevZdroje	Journal of Molecular Structure
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	826
http://linked.open...iv/tvurceVysledku	Marek, Jaromír Ali, Mahammad Mijanuddin, M. d. Mondal, Parikshit Chandra Ray, Ambarish
http://linked.open...n/vavai/riv/zamer	Physical and chemical properties of advanced materials and structures
issn	0022-2860
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	14310
is http://linked.open...avai/riv/vysledek of	Copper(II) complexes of tridentate selenobisphenolate ligand in mixed ligand environments: Synthesis, crystal structure, EPR and electrochemical studies Copper(II) complexes of tridentate selenobisphenolate ligand in mixed ligand environments: Synthesis, crystal structure, EPR and electrochemical studies Copper(II) complexes of tridentate selenobisphenolate ligand in mixed ligand environments: Synthesis, crystal structure, EPR and electrochemical studies

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