About: New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 x 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy

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About: New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 x 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	New ethylenediammonium diphosphates (NH3(CH2)(2)NH3)(2)[Me(HP2O7)(2) center dot 2H(2)O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group PT The unit-cell parameters are: a = 7.5211(6) A, b = 7.5574(3) angstrom, c = 9.7689(7) angstrom, a = 103.6(1)degrees, beta = 111.14(1)degrees, gamma = 98.04(1)degrees, V = 486.9(l) angstrom(3) (1) and a = 7.4631(15) angstrom, b = 7.5274(12) angstrom, c = 9.743(3) angstrom, alpha = 104.28(2)degrees, beta = 110.75(2)degrees, gamma = 97.50(2)degrees, V = 481.4(2) angstrom(3) (2). The three-dimensional network is built up by discrete Me(HP2O7)(2) center dot 2H(2)O moieties, which, via strong O-H center dot center dot center dot O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H center dot center dot center dot O bonds. New ethylenediammonium diphosphates (NH3(CH2)(2)NH3)(2)[Me(HP2O7)(2) center dot 2H(2)O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group PT The unit-cell parameters are: a = 7.5211(6) A, b = 7.5574(3) angstrom, c = 9.7689(7) angstrom, a = 103.6(1)degrees, beta = 111.14(1)degrees, gamma = 98.04(1)degrees, V = 486.9(l) angstrom(3) (1) and a = 7.4631(15) angstrom, b = 7.5274(12) angstrom, c = 9.743(3) angstrom, alpha = 104.28(2)degrees, beta = 110.75(2)degrees, gamma = 97.50(2)degrees, V = 481.4(2) angstrom(3) (2). The three-dimensional network is built up by discrete Me(HP2O7)(2) center dot 2H(2)O moieties, which, via strong O-H center dot center dot center dot O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H center dot center dot center dot O bonds. (en)
Title	New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 x 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 x 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy (en)
skos:prefLabel	New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 x 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 x 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy (en)
skos:notation	RIV/00216224:14310/06:00018630!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 143100011)
http://linked.open...iv/cisloPeriodika	221
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Žák, Zdirad Taraba, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	488521
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/06:00018630
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	diphosphate; ethylenediammonium; Raman and infrared spectroscopy; X-ray diffraction; single crystal structure analysis (en)
http://linked.open.../riv/klicoveSlovo	diphosphate ethylenediammonium X-ray diffraction Raman and infrared spectroscopy single crystal structure analysis
http://linked.open...odStatuVydavatele	IT - Italská republika
http://linked.open...ontrolniKodProRIV	[ADC2DAFF5586]
http://linked.open...i/riv/nazevZdroje	Zeitschrift für Kristallographie
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	9/2006
http://linked.open...iv/tvurceVysledku	Žák, Zdirad Taraba, Jan Capitelli, Francesco El Bali, Brahim Essehli, Rachid Lachkar, Mohammed Mattei, Giorgio Valentini, Veronica
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20143100011
issn	0044-2968
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	14310
is http://linked.open...avai/riv/vysledek of	New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 x 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 x 2 H2O] [Me = Co, Ni]: X-ray crystal structure and vibrational spectroscopy

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