About: Spatial resolution of degradation in stabilized polystyrene and polypropylene plaques exposed to accelerated photodegradation or heat aging     Goto   Sponge   NotDistinct   Permalink

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  • Spatial resolution of photo and thermooxidation processes in polypropylene (PP) and polystyrene (PS) plaques was studied by electron spin resonance imaging (ESRI) and attenuated total reflectance Fourier-transform infrared spectroscopy (ATR FTIR). Polymer plaques made of PP and PS stabilized with various systems based on hindered amine stabilizers (HAS) were exposed to accelerated photodegradation and to heat aging in air atmosphere. Concentration profiles of nitroxides generated during the degradation process in the plaques were measured by ESRI, carbonyl and hydroxy groups were identified by ATR FTIR, transparency of the plaques in the actinic part of solar radiation, including a part of UV-B (295e315 nm), full range of UV-A (315e400 nm) and visible radiation was measured by optical techniques. A mechanism of the degradation consistent with all experimental data is suggested.
  • Spatial resolution of photo and thermooxidation processes in polypropylene (PP) and polystyrene (PS) plaques was studied by electron spin resonance imaging (ESRI) and attenuated total reflectance Fourier-transform infrared spectroscopy (ATR FTIR). Polymer plaques made of PP and PS stabilized with various systems based on hindered amine stabilizers (HAS) were exposed to accelerated photodegradation and to heat aging in air atmosphere. Concentration profiles of nitroxides generated during the degradation process in the plaques were measured by ESRI, carbonyl and hydroxy groups were identified by ATR FTIR, transparency of the plaques in the actinic part of solar radiation, including a part of UV-B (295e315 nm), full range of UV-A (315e400 nm) and visible radiation was measured by optical techniques. A mechanism of the degradation consistent with all experimental data is suggested. (en)
Title
  • Spatial resolution of degradation in stabilized polystyrene and polypropylene plaques exposed to accelerated photodegradation or heat aging
  • Spatial resolution of degradation in stabilized polystyrene and polypropylene plaques exposed to accelerated photodegradation or heat aging (en)
skos:prefLabel
  • Spatial resolution of degradation in stabilized polystyrene and polypropylene plaques exposed to accelerated photodegradation or heat aging
  • Spatial resolution of degradation in stabilized polystyrene and polypropylene plaques exposed to accelerated photodegradation or heat aging (en)
skos:notation
  • RIV/00216224:14310/06:00016625!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021622410)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 500647
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/06:00016625
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Photodegradation; Photostabilization; HAS; Thermal aging; Polystyrene; Polypropylene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [D9834C6C7BBD]
http://linked.open...i/riv/nazevZdroje
  • Polymer Degradation and Stability
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 91
http://linked.open...iv/tvurceVysledku
  • Pospíšil, J.
  • Humlíček, Josef
  • Schmidt, P.
  • Marek, A.
  • Kaprálková, L.
  • Pfleger, J.
  • Pilař, J.
http://linked.open...n/vavai/riv/zamer
issn
  • 0141-3910
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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