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  • Broadband dielec. relaxation spectroscopy (DRS), thermally stimulated depolarisation currents (TSDC), differential scanning calorimetry (DSC) and to a lesser extent water uptake measurements, were employed to investigate mol. mobility, morphol. and crystn./melting events of PEG in poly(imide-amide)-polyethylene glycol hybrid networks (PIA-PEG) with short (M n=1000 g/mol) and long (M n=3400 g/mol) PEG crosslinks. The results obtained suggest long range connectivity of the PEG component in the hybrids with short PEG crosslinks at PEG content higher than 40 wt% and in these with long PEG crosslinks at PEG content higher than 20 wt%. Crystn. of the PEG component is obsd. by DSC in the hybrids with the longer crosslinks at sufficiently high content of PEG, only. The glass transition temp., T g, of PEG component in the hybrids with the shorter PEG crosslinks is shifted to higher temps.
  • Broadband dielec. relaxation spectroscopy (DRS), thermally stimulated depolarisation currents (TSDC), differential scanning calorimetry (DSC) and to a lesser extent water uptake measurements, were employed to investigate mol. mobility, morphol. and crystn./melting events of PEG in poly(imide-amide)-polyethylene glycol hybrid networks (PIA-PEG) with short (M n=1000 g/mol) and long (M n=3400 g/mol) PEG crosslinks. The results obtained suggest long range connectivity of the PEG component in the hybrids with short PEG crosslinks at PEG content higher than 40 wt% and in these with long PEG crosslinks at PEG content higher than 20 wt%. Crystn. of the PEG component is obsd. by DSC in the hybrids with the longer crosslinks at sufficiently high content of PEG, only. The glass transition temp., T g, of PEG component in the hybrids with the shorter PEG crosslinks is shifted to higher temps. (en)
Title
  • Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks
  • Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks (en)
skos:prefLabel
  • Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks
  • Structure-property relationships in novel poly(imide-amide)-poly(ethylene glycol) hybrid networks (en)
skos:notation
  • RIV/00216224:14310/06:00016589!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/03/0388), S, V
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 502017
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/06:00016589
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • DRS; TSDC; hybrid networks (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [A97CF84D04D5]
http://linked.open...i/riv/nazevZdroje
  • Polymer
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 47
http://linked.open...iv/tvurceVysledku
  • Sysel, Petr
  • Šindelář, Vladimír
  • Pissis, P.
  • Bershtein, V. A.
  • Kripotou, S.
http://linked.open...ain/vavai/riv/wos
  • 000234617600047
issn
  • 0032-3861
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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