About: Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A series of binuclear complexes of a general formula [(dppbO2)Ln(NO3)3(l-dppbO2)Ln(NO3)3(dppbO2)] (Ln = Pr (1), Nd (2), Sm (3), Dy (4), Lu (5)) were prepared by reacting bis(diphenylphosphino)butane dioxide (dppbO2) with lanthanide nitrates under solvothermal conditions. All compounds were characterized by analytical and spectroscopic techniques, such as infrared spectroscopy and mass spectrometry with electrospray ionization, and their molecular structures were determined by single crystal X-ray diffraction analysis in four cases. In contrast to the majority of lanthanide complexes with bis(diphenylphosphino)ethane dioxide which were previously reported as 2D polymeric networks, the present compounds are strictly molecular. This is evidently manifestation of the longer and flexible ligand backbone that allows a chelating binding mode. A series of binuclear complexes of a general formula [(dppbO2)Ln(NO3)3(l-dppbO2)Ln(NO3)3(dppbO2)] (Ln = Pr (1), Nd (2), Sm (3), Dy (4), Lu (5)) were prepared by reacting bis(diphenylphosphino)butane dioxide (dppbO2) with lanthanide nitrates under solvothermal conditions. All compounds were characterized by analytical and spectroscopic techniques, such as infrared spectroscopy and mass spectrometry with electrospray ionization, and their molecular structures were determined by single crystal X-ray diffraction analysis in four cases. In contrast to the majority of lanthanide complexes with bis(diphenylphosphino)ethane dioxide which were previously reported as 2D polymeric networks, the present compounds are strictly molecular. This is evidently manifestation of the longer and flexible ligand backbone that allows a chelating binding mode. (en)
Title	Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide (en)
skos:prefLabel	Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide (en)
skos:notation	RIV/00216224:14310/06:00015583!RIV10-MSM-14310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/04/0296), Z(MSM0021622410), Z(MSM0021622415)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Nečas, Marek Pinkas, Jiří Zdráhal, Zbyněk Spíchal, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	466931
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/06:00015583
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	lanthanide complexes coordination polymers (en)
http://linked.open.../riv/klicoveSlovo	lanthanide complexes coordination polymers
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[7FF02AE7F9E4]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Sonochemical synthesis of oxide and phosphate materials
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	25
http://linked.open...iv/tvurceVysledku	Nečas, Marek Pinkas, Jiří Zdráhal, Zbyněk Spíchal, Zdeněk
http://linked.open...ain/vavai/riv/wos	000248633900025
http://linked.open...n/vavai/riv/zamer	Molecular basis of cell and tissue regulations Physical and chemical properties of advanced materials and structures
issn	0277-5387
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	14310
is http://linked.open...avai/riv/vysledek of	Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide

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