About: Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set.     Goto   Sponge   NotDistinct   Permalink

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Description
  • We are introducing a new structural pattern 3 based on highly strained bicylo[1.1.1]pentane cage, which benefits from placing additional functionalities (FG) on its bridge positions. The new substituents are on two parallel bonds in positions 2 and 4, perpendicular to 1-3 axis of the cage. Such configuration enables interaction of the functionalities in an .equatorial. plane of the cage defined by its rotation around the 1-3 axis. If used in staffanes, these functionalities (polarizable, electron donating or accepting, ionizable, etc.) can propagate the interaction along the light of such molecular rod.
  • We are introducing a new structural pattern 3 based on highly strained bicylo[1.1.1]pentane cage, which benefits from placing additional functionalities (FG) on its bridge positions. The new substituents are on two parallel bonds in positions 2 and 4, perpendicular to 1-3 axis of the cage. Such configuration enables interaction of the functionalities in an .equatorial. plane of the cage defined by its rotation around the 1-3 axis. If used in staffanes, these functionalities (polarizable, electron donating or accepting, ionizable, etc.) can propagate the interaction along the light of such molecular rod. (en)
  • We are introducing a new structural pattern 3 based on highly strained bicylo[1.1.1]pentane cage, which benefits from placing additional functionalities (FG) on its bridge positions. The new substituents are on two parallel bonds in positions 2 and 4, perpendicular to 1-3 axis of the cage. Such configuration enables interaction of the functionalities in an .equatorial. plane of the cage defined by its rotation around the 1-3 axis. If used in staffanes, these functionalities (polarizable, electron donating or accepting, ionizable, etc.) can propagate the interaction along the light of such molecular rod. (cs)
Title
  • Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set.
  • Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set. (en)
  • Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set. (cs)
skos:prefLabel
  • Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set.
  • Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set. (en)
  • Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set. (cs)
skos:notation
  • RIV/00216224:14310/04:00010948!RIV09-MSM-14310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ME 571), Z(MSM 143100011)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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  • 588933
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/04:00010948
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • bicyclopentanes; staffanes (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [D419F4CD067F]
http://linked.open...v/mistoKonaniAkce
  • Praha
http://linked.open...i/riv/mistoVydani
  • Praha
http://linked.open...i/riv/nazevZdroje
  • Chemické listy, International Conference on Supramolecular Science & Technology, ICSS&T 2004 Congress Abstract Book
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Mazal, Ctibor
  • Michl, Josef
  • Bartoš, Petr
  • Škarka, Ondřej
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
issn
  • 0009-2770
number of pages
http://purl.org/ne...btex#hasPublisher
  • Česká společnost chemická
http://localhost/t...ganizacniJednotka
  • 14310
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