About: Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2]

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About: Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The reaction between transition metal salts, M(ClO4 )2.6H2O (M = Co, Mn, Cu), sodium dicyanamide, NaN(CN)2 , and 4,4-bipyridine-N,N-dioxide, bpno, leads to three new complexes: [Co(bpno)2{N(CN)2}2(H2O)2] 1, [Mn(bpno)2{N(CN)2}2(H2O)2]2, and [Cu(bpno){N(CN)2}2(H2O)] 3. In the three compounds, the N(CN)2 ions act as monodentate ligands through one of the CN groups. Compounds 1 and 2 are isomorphous. Both bpno molecules are terminal ligands. The metal ions, cobalt(II) and manganese(II), display an octahedral stereochemistry and are located on an inversion center. In compound 3, the bpno molecules act as bridging ligands and support the formation of infinite chains. The copper(II) ions are pentacoordinated. The packing diagrams of the three compounds reveal interesting supramolecular solid-state architectures. Compounds 1 and 2 are two-dimensional hydrogen bonded polymers, which are formed by the interaction of the bpno and dicyanamido ligands with the aqua ligands of neighboring [M(bpno)2{N(CN)2}2(H2O)2] The reaction between transition metal salts, M(ClO4 )2.6H2O (M = Co, Mn, Cu), sodium dicyanamide, NaN(CN)2 , and 4,4-bipyridine-N,N-dioxide, bpno, leads to three new complexes: [Co(bpno)2{N(CN)2}2(H2O)2] 1, [Mn(bpno)2{N(CN)2}2(H2O)2]2, and [Cu(bpno){N(CN)2}2(H2O)] 3. In the three compounds, the N(CN)2 ions act as monodentate ligands through one of the CN groups. Compounds 1 and 2 are isomorphous. Both bpno molecules are terminal ligands. The metal ions, cobalt(II) and manganese(II), display an octahedral stereochemistry and are located on an inversion center. In compound 3, the bpno molecules act as bridging ligands and support the formation of infinite chains. The copper(II) ions are pentacoordinated. The packing diagrams of the three compounds reveal interesting supramolecular solid-state architectures. Compounds 1 and 2 are two-dimensional hydrogen bonded polymers, which are formed by the interaction of the bpno and dicyanamido ligands with the aqua ligands of neighboring [M(bpno)2{N(CN)2}2(H2O)2] (en) The reaction between transition metal salts, M(ClO4 )2.6H2O (M = Co, Mn, Cu), sodium dicyanamide, NaN(CN)2 , and 4,4-bipyridine-N,N-dioxide, bpno, leads to three new complexes: [Co(bpno)2{N(CN)2}2(H2O)2] 1, [Mn(bpno)2{N(CN)2}2(H2O)2]2, and [Cu(bpno){N(CN)2}2(H2O)] 3. In the three compounds, the N(CN)2 ions act as monodentate ligands through one of the CN groups. Compounds 1 and 2 are isomorphous. Both bpno molecules are terminal ligands. The metal ions, cobalt(II) and manganese(II), display an octahedral stereochemistry and are located on an inversion center. In compound 3, the bpno molecules act as bridging ligands and support the formation of infinite chains. The copper(II) ions are pentacoordinated. The packing diagrams of the three compounds reveal interesting supramolecular solid-state architectures. Compounds 1 and 2 are two-dimensional hydrogen bonded polymers, which are formed by the interaction of the bpno and dicyanamido ligands with the aqua ligands of neighboring [M(bpno)2{N(CN)2}2(H2O)2] (cs)
Title	Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2] Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2] (en) Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2] (cs)
skos:prefLabel	Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2] Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2] (en) Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2] (cs)
skos:notation	RIV/00216224:14310/03:00007959!RIV09-GA0-14310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA203/01/1533)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Žák, Zdirad Pinkas, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykova univerzita / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	629762
http://linked.open...ai/riv/idVysledku	RIV/00216224:14310/03:00007959
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	supramolecular; bipyridine; cobalt; manganese; copper; dicyanamido (en)
http://linked.open.../riv/klicoveSlovo	cobalt copper supramolecular manganese bipyridine dicyanamido
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[78818ABF0659]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	22
http://linked.open...iv/tvurceVysledku	Pinkas, Jiří Žák, Zdirad Andruh, Marius Madalan, Augustin M. Nedelcu, Aneta
issn	0277-5387
number of pages	6 (xsd:int)
http://localhost/t...ganizacniJednotka	14310

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