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| Description
| - Mixed-ligand binuclear Cu(II) complexes involving thiodiglycolate(2-) anion and nitrogen-donor ligands in the coordination sphere of composition [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2.5H2O (1) and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2 (2), where PHEN=1,10-phenanthroline, H2tdga=thiodiglycolic acid, PMDIEN=N,N,N',N',N''-pentamethyldiethylenetriamine, have been prepared. Temperature dependence of magnetic susceptibility, EPR spectroscopy and single crystal X-ray analysis has been used to characterize these compounds. Magnetic susceptibility measurements over the 1.9-300 K temperature range revealed a weak antiferromagnetic interaction between two copper atoms with the exchange integral value 2J=-4.80 cm-1 for 1 and -0.71 cm-1 for 2. The bridging dianion of thiodiglycolic acid is coordinated in each of the two complexes in a different manner.
- Mixed-ligand binuclear Cu(II) complexes involving thiodiglycolate(2-) anion and nitrogen-donor ligands in the coordination sphere of composition [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2.5H2O (1) and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2 (2), where PHEN=1,10-phenanthroline, H2tdga=thiodiglycolic acid, PMDIEN=N,N,N',N',N''-pentamethyldiethylenetriamine, have been prepared. Temperature dependence of magnetic susceptibility, EPR spectroscopy and single crystal X-ray analysis has been used to characterize these compounds. Magnetic susceptibility measurements over the 1.9-300 K temperature range revealed a weak antiferromagnetic interaction between two copper atoms with the exchange integral value 2J=-4.80 cm-1 for 1 and -0.71 cm-1 for 2. The bridging dianion of thiodiglycolic acid is coordinated in each of the two complexes in a different manner. (en)
- Mixed-ligand binuclear Cu(II) complexes involving thiodiglycolate(2-) anion and nitrogen-donor ligands in the coordination sphere of composition [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 . 5H2O (1) and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2 (2), where PHEN=1,10-phenanthroline, H2tdga=thiodiglycolic acid, PMDIEN=N,N,N',N',N''-pentamethyldiethylenetriamine, have been prepared. Temperature dependence of magnetic susceptibility, EPR spectroscopy and single crystal X-ray analysis has been used to characterize these compounds. Magnetic susceptibility measurements over the 1.9-300 K temperature range revealed a weak antiferromagnetic interaction between two copper atoms with the exchange integral value 2J=-4.80 cm-1 for 1 and -0.71 cm-1 for 2. The bridging dianion of thiodiglycolic acid is coordinated in each of the two complexes in a different manner. (cs)
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| Title
| - The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2
- The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2 (en)
- The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2 (cs)
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| skos:prefLabel
| - The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2
- The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2 (en)
- The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2 (cs)
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| skos:notation
| - RIV/00216224:14310/03:00007940!RIV08-GA0-14310___
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| http://linked.open.../vavai/riv/strany
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/00216224:14310/03:00007940
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - structure; copper(II); thiodiglycolic acid (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...vavai/riv/projekt
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Marek, Jaromír
- Trávníček, Z.
- Kopel, P.
- Mrozinski, J.
- Korabik, M.
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| issn
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| number of pages
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| http://localhost/t...ganizacniJednotka
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