About: Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations     Goto   Sponge   NotDistinct   Permalink

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Description
  • The title compounds 2 (Z = OH, Cl, Br, OCH3, mesyl, tosyl, 3,4-(methylenedioxy)phenoxy) are synthetic precursors of an antidepressive drug paroxetine 1 [1]. Chiral recognition of 2 was observed by NMR spectroscopy in the presence of (S)-Mosher acid 5. For most substrates in the series, the non-equivalence induced in their 1H and 19F NMR spectra was sufficiently large to allow the evaluation of enantiomeric purity [2].
  • The title compounds 2 (Z = OH, Cl, Br, OCH3, mesyl, tosyl, 3,4-(methylenedioxy)phenoxy) are synthetic precursors of an antidepressive drug paroxetine 1 [1]. Chiral recognition of 2 was observed by NMR spectroscopy in the presence of (S)-Mosher acid 5. For most substrates in the series, the non-equivalence induced in their 1H and 19F NMR spectra was sufficiently large to allow the evaluation of enantiomeric purity [2]. (en)
  • The title compounds 2 (Z = OH, Cl, Br, OCH3, mesyl, tosyl, 3,4-(methylenedioxy)phenoxy) are synthetic precursors of an antidepressive drug paroxetine 1 [1]. Chiral recognition of 2 was observed by NMR spectroscopy in the presence of (S)-Mosher acid 5. For most substrates in the series, the non-equivalence induced in their 1H and 19F NMR spectra was sufficiently large to allow the evaluation of enantiomeric purity [2]. (cs)
Title
  • Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations
  • Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations (en)
  • Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations (cs)
skos:prefLabel
  • Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations
  • Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations (en)
  • Trans-4-(4-fluorophenyl)-3-substituted-1-methylpiperidines: Chiral recognition and Transformations (cs)
skos:notation
  • RIV/00216224:14310/02:00007021!RIV08-MSM-14310___
http://linked.open.../vavai/riv/strany
  • 91
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(OC D10.20), Z(MSM 143100011)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 667330
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/02:00007021
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • chiral recognition; microwave irradiation; racemization (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [05F952AA9907]
http://linked.open...v/mistoKonaniAkce
  • 8.-12.9.2002; Hamburg, Německo
http://linked.open...i/riv/mistoVydani
  • Hamburg, Německo
http://linked.open...i/riv/nazevZdroje
  • Book of Abstracts from the 14th International Symposium on Chirality
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Navrátilová, Hana
  • Potáček, Milan
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Hamburg University
http://localhost/t...ganizacniJednotka
  • 14310
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