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  • We deposited protective coatings on polycarbonates from hexamethyldisiloxane (HMDSO) and HMDSO/O2 mixtures by plasma enhanced CVD method. We studied especially deposition rate, optical constants in UV/VIS, film composition and mechanical properties in dependence on rf power and oxygen to HMDSO flow rate ratio. Plasma polymer HMDSO films (PP-HMDSO)showed good transparency in the visible and increased absorption in UV region. The optical constants of HMDSO/O2 films were similar to the tabulated SiO2. In general, the films were characterised by a relative high content of hydrogen (22-66 %) and a carbon content below 20 %. The films deposited at the oxygen to HMDSO flow rate ratio higher than 15 exhibit higher tensile stress and higher hardness than those prepared at ratios of 5-10. The nature of the internal stress changed to compressive for PP-HMDSO. Plasma pretreatment of polycarbonate in argon significantly improved the film adherence especially when low powers and short treatment times were used.
  • We deposited protective coatings on polycarbonates from hexamethyldisiloxane (HMDSO) and HMDSO/O2 mixtures by plasma enhanced CVD method. We studied especially deposition rate, optical constants in UV/VIS, film composition and mechanical properties in dependence on rf power and oxygen to HMDSO flow rate ratio. Plasma polymer HMDSO films (PP-HMDSO)showed good transparency in the visible and increased absorption in UV region. The optical constants of HMDSO/O2 films were similar to the tabulated SiO2. In general, the films were characterised by a relative high content of hydrogen (22-66 %) and a carbon content below 20 %. The films deposited at the oxygen to HMDSO flow rate ratio higher than 15 exhibit higher tensile stress and higher hardness than those prepared at ratios of 5-10. The nature of the internal stress changed to compressive for PP-HMDSO. Plasma pretreatment of polycarbonate in argon significantly improved the film adherence especially when low powers and short treatment times were used. (en)
Title
  • Plasma modification of polycarbonates
  • Plasma modification of polycarbonates (en)
skos:prefLabel
  • Plasma modification of polycarbonates
  • Plasma modification of polycarbonates (en)
skos:notation
  • RIV/00216224:14310/01:00004619!RIV/2002/MSM/143102/N
http://linked.open.../vavai/riv/strany
  • 449
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA202/00/P037), P(GV106/96/K245), P(GV202/97/K038), P(KSK1010104), P(VS96084), Z(AV0Z1048901), Z(MSM 143100003)
http://linked.open...iv/cisloPeriodika
  • 142-144
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 691252
http://linked.open...ai/riv/idVysledku
  • RIV/00216224:14310/01:00004619
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Plasma modification of polycarbonates (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [6410D218F836]
http://linked.open...i/riv/nazevZdroje
  • Surface & coatings technology
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2001
http://linked.open...iv/tvurceVysledku
  • Buršíková, Vilma
  • Janča, Jan
  • Macková, Anna
  • Zajíčková, Lenka
  • Peřina, Vratislav
  • Smirnov, Sergej
  • Subedi, Deepak Prasad
http://linked.open...n/vavai/riv/zamer
issn
  • 0257-8972
number of pages
http://localhost/t...ganizacniJednotka
  • 14310
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