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  • Determination of fluorescence or photo- and electro-luminescence quantum yield (QY) is of increasing importance for standardization of novel light-emitting materials like semiconductor quantum dots. The most straightforward spectroscopic QY measurement technique is based on the exploitation of an integrating sphere (IS). We propose a compact set-up and procedure for reliable measurements of QY over a broad excitation spectral range which uses excitation by light-emitting diodes. Starting from the general IS theory we show that (i) a variable excitation pattern has no fatal influence on the QY determination and (ii) a simple two-configuration experiment is an adequate basis of the correct experimental procedure. Then we give guidelines for the QY experiment and calculations as well as a few practical examples and error analysis. Our comprehensive description of absolute luminescenceQYtechniques based on the IS theory has a general applicability not restricted to the apparatus described in this paper.
  • Determination of fluorescence or photo- and electro-luminescence quantum yield (QY) is of increasing importance for standardization of novel light-emitting materials like semiconductor quantum dots. The most straightforward spectroscopic QY measurement technique is based on the exploitation of an integrating sphere (IS). We propose a compact set-up and procedure for reliable measurements of QY over a broad excitation spectral range which uses excitation by light-emitting diodes. Starting from the general IS theory we show that (i) a variable excitation pattern has no fatal influence on the QY determination and (ii) a simple two-configuration experiment is an adequate basis of the correct experimental procedure. Then we give guidelines for the QY experiment and calculations as well as a few practical examples and error analysis. Our comprehensive description of absolute luminescenceQYtechniques based on the IS theory has a general applicability not restricted to the apparatus described in this paper. (en)
Title
  • Determination of absolute luminescence quantum yields of luminescing nanomaterials over a broad spectral range: From the integrating sphere theory to the correct methodology
  • Determination of absolute luminescence quantum yields of luminescing nanomaterials over a broad spectral range: From the integrating sphere theory to the correct methodology (en)
skos:prefLabel
  • Determination of absolute luminescence quantum yields of luminescing nanomaterials over a broad spectral range: From the integrating sphere theory to the correct methodology
  • Determination of absolute luminescence quantum yields of luminescing nanomaterials over a broad spectral range: From the integrating sphere theory to the correct methodology (en)
skos:notation
  • RIV/00216208:11320/14:10290878!RIV15-MSM-11320___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 10728
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11320/14:10290878
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • nanocrystals; radiometry; efficiency; quantum yield; luminescence (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [9247365D4D0C]
http://linked.open...i/riv/nazevZdroje
  • Nanoscience Methods
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 3
http://linked.open...iv/tvurceVysledku
  • Valenta, Jan
issn
  • 2164-2311
number of pages
http://bibframe.org/vocab/doi
  • 10.1080/21642311.2014.884288
http://localhost/t...ganizacniJednotka
  • 11320
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