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Description
  • In the present work, zirconia (ZrO2) nanopowders doped with yttria (Y2O3) and chromia (Cr2O3) were prepared by a co-precipitation technique. The nanopowders were then subjected to a calcination and a successive sintering at elevated temperatures up to 1500 C. The nanostructures in these nanomaterials were characterized by positron annihilation spectroscopy (positron lifetimes and Doppler broadening measurements) which is a non-destructive technique with a high sensitivity to atomic-scale open-volume defects. It was found that the zirconia-based nanomaterials studied contain vacancy-like defects and nano-scale pores. Diffusion processes induced in these nanomaterials by sintering were investigated also by depth sensitive positron annihilation studies using a variable energy slow positron beam. Sintering was found to cause intensive grain growth and a removal of porosity by a migration of pores from the sample interior toward its surface.
  • In the present work, zirconia (ZrO2) nanopowders doped with yttria (Y2O3) and chromia (Cr2O3) were prepared by a co-precipitation technique. The nanopowders were then subjected to a calcination and a successive sintering at elevated temperatures up to 1500 C. The nanostructures in these nanomaterials were characterized by positron annihilation spectroscopy (positron lifetimes and Doppler broadening measurements) which is a non-destructive technique with a high sensitivity to atomic-scale open-volume defects. It was found that the zirconia-based nanomaterials studied contain vacancy-like defects and nano-scale pores. Diffusion processes induced in these nanomaterials by sintering were investigated also by depth sensitive positron annihilation studies using a variable energy slow positron beam. Sintering was found to cause intensive grain growth and a removal of porosity by a migration of pores from the sample interior toward its surface. (en)
Title
  • Defects and sintering-induced diffusion processes in yttria-stabilised zirconia nanomaterials studied by positron annihilation spectroscopy
  • Defects and sintering-induced diffusion processes in yttria-stabilised zirconia nanomaterials studied by positron annihilation spectroscopy (en)
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  • Defects and sintering-induced diffusion processes in yttria-stabilised zirconia nanomaterials studied by positron annihilation spectroscopy
  • Defects and sintering-induced diffusion processes in yttria-stabilised zirconia nanomaterials studied by positron annihilation spectroscopy (en)
skos:notation
  • RIV/00216208:11320/14:10290420!RIV15-MSM-11320___
http://linked.open...avai/riv/aktivita
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  • I, P(GAP108/11/1396)
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  • 10002
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  • RIV/00216208:11320/14:10290420
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  • Zirconia; Sintering; Positron Annihilation; Porosity; Nanopowder (en)
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  • [A65EA8835460]
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  • Switzerland
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  • 1
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  • Diffusion in Advanced Materials
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  • Anwand, Wolfgang
  • Melikhova, Oksana
  • Procházka, Ivan
  • Čížek, Jakub
  • Danilenko, Igor A.
  • Konstantinova, Tetyana E.
number of pages
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  • 10.4028/www.scientific.net/DF.1.155
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  • TRANS TECH PUBLICATIONS LTD
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  • 978-3-03835-081-1
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  • 11320
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