About: Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules     Goto   Sponge   NotDistinct   Permalink

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  • The transformation of Mn-II glycolates (glc) between the three-dimensional coordination polymer [Mn(glc)(2)](n) (1) and discrete mononuclear phase [Mn(glc)(2)(H2O)(2)] (2) can be reversibly switched by water molecules, which dramatically change the magnetocaloric effect (MCE) of Mn-II glycolates from the maximum of 6.9Jkg(-1)K(-1) in 1 to 60.3Jkg(-1)K(-1) in 2. This case example reveals that the effect of magnetic coupling on MCE plays a dominant role over that of other factors such as magnetic density for 3d-type magnetic refrigerants.
  • The transformation of Mn-II glycolates (glc) between the three-dimensional coordination polymer [Mn(glc)(2)](n) (1) and discrete mononuclear phase [Mn(glc)(2)(H2O)(2)] (2) can be reversibly switched by water molecules, which dramatically change the magnetocaloric effect (MCE) of Mn-II glycolates from the maximum of 6.9Jkg(-1)K(-1) in 1 to 60.3Jkg(-1)K(-1) in 2. This case example reveals that the effect of magnetic coupling on MCE plays a dominant role over that of other factors such as magnetic density for 3d-type magnetic refrigerants. (en)
Title
  • Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules
  • Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules (en)
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  • Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules
  • Switching of the Magnetocaloric Effect of Mn-II Glycolate by Water Molecules (en)
skos:notation
  • RIV/00216208:11320/14:10271606!RIV15-MSM-11320___
http://linked.open...avai/riv/aktivita
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  • I, P(LM2011025)
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  • 11
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  • 48854
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  • RIV/00216208:11320/14:10271606
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  • manganese; magnetocaloric effect; magnetic properties; glycolates; coordination polymers (en)
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  • DE - Spolková republika Německo
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  • [7029A409D624]
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  • Chemistry - A European Journal
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  • 20
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  • Prokleška, Jan
  • Sechovský, Vladimír
  • Leng, Ji-Dong
  • Tong, Ming-Liang
  • Orendac, Martin
  • Chen, Yan-Cong
  • Guo, Fu-Sheng
  • Liu, Jun-Liang
  • Vrabel, Peter
http://linked.open...ain/vavai/riv/wos
  • 000332043500010
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  • 0947-6539
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http://bibframe.org/vocab/doi
  • 10.1002/chem.201304423
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  • 11320
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