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  • In the present work hydrothermally grown ZnO single crystals were electrochemically charged with hydrogen. The influence of hydrogen on ZnO microstructure was investigated by positron annihilation spectroscopy (PAS) combined with X-ray diffraction (XRD) using synchrotron radiation. Hydrogen concentration in the samples was determined by nuclear reaction analysis (NRA). It was found that a high concentration of hydrogen can be introduced into ZnO by electrochemical loading. At low concentrations absorbed hydrogen causes elastic volume expansion of ZnO crystal. At higher concentration, hydrogen-induced stresses exceed the yield stress in ZnO and plastic deformation of the crystal takes place leading to formation a defected subsurface layer in the crystals.
  • In the present work hydrothermally grown ZnO single crystals were electrochemically charged with hydrogen. The influence of hydrogen on ZnO microstructure was investigated by positron annihilation spectroscopy (PAS) combined with X-ray diffraction (XRD) using synchrotron radiation. Hydrogen concentration in the samples was determined by nuclear reaction analysis (NRA). It was found that a high concentration of hydrogen can be introduced into ZnO by electrochemical loading. At low concentrations absorbed hydrogen causes elastic volume expansion of ZnO crystal. At higher concentration, hydrogen-induced stresses exceed the yield stress in ZnO and plastic deformation of the crystal takes place leading to formation a defected subsurface layer in the crystals. (en)
Title
  • Hydrogen interaction with defects in ZnO
  • Hydrogen interaction with defects in ZnO (en)
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  • Hydrogen interaction with defects in ZnO
  • Hydrogen interaction with defects in ZnO (en)
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  • RIV/00216208:11320/13:10189468!RIV14-GA0-11320___
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  • I, P(GAP108/11/0958), S, Z(MSM0021620834)
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  • 78475
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  • RIV/00216208:11320/13:10189468
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  • positron annihilation spectroscopy; hydrogen defects; zinc oxide (en)
http://linked.open.../riv/klicoveSlovo
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  • [5E757B86C3F4]
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  • Smolenice
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  • STAFA-ZURICH
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  • Materials Science Forum
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  • Anwand, Wolfgang
  • Brauer, Gerhard
  • Baehtz, Carsten
  • Lukáč, František
  • Procházka, Ivan
  • Uchida, Helmut
  • Vlach, Martin
  • Vlček, Marián
  • Wagner, Stefan
  • Čížek, Jakub
  • Becker, Hans-Werner
  • Rogalla, Detlef
  • Traeger, Franziska
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  • 000315535700047
http://linked.open.../riv/zahajeniAkce
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issn
  • 0255-5476
number of pages
http://bibframe.org/vocab/doi
  • 10.4028/www.scientific.net/MSF.733.228
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  • TRANS TECH PUBLICATIONS LTD
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  • 11320
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