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Description
  • ZnO single crystals electrochemically charged with hydrogen were characterized. The concentration of hydrogen introduced into the crystals was determined by nuclear reaction analysis and was found to be in a reasonable agreement with the value estimated from the Faraday's law. Moreover, a sub-surface layer with very high concentration of hydrogen and very high density of open-volume defects was formed by plastic deformation caused by hydrogen-induced stress. Specific surface modification caused by hydrogen-induced slip in the c-direction was observed on hydrogen loaded crystals. Hydrogen diffusion coefficient in ZnO was estimated by in situ electrical resistivity measurement. It was found that hydrogen diffusion in the c-direction is faster than in the a-direction most probably due to open channels existing in the wurtzite structure along the c-axis.
  • ZnO single crystals electrochemically charged with hydrogen were characterized. The concentration of hydrogen introduced into the crystals was determined by nuclear reaction analysis and was found to be in a reasonable agreement with the value estimated from the Faraday's law. Moreover, a sub-surface layer with very high concentration of hydrogen and very high density of open-volume defects was formed by plastic deformation caused by hydrogen-induced stress. Specific surface modification caused by hydrogen-induced slip in the c-direction was observed on hydrogen loaded crystals. Hydrogen diffusion coefficient in ZnO was estimated by in situ electrical resistivity measurement. It was found that hydrogen diffusion in the c-direction is faster than in the a-direction most probably due to open channels existing in the wurtzite structure along the c-axis. (en)
Title
  • Hydrogen absorption and diffusivity in ZnO single crystals
  • Hydrogen absorption and diffusivity in ZnO single crystals (en)
skos:prefLabel
  • Hydrogen absorption and diffusivity in ZnO single crystals
  • Hydrogen absorption and diffusivity in ZnO single crystals (en)
skos:notation
  • RIV/00216208:11320/13:10189245!RIV14-GA0-11320___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP108/11/0958), P(LH12173), S
http://linked.open...iv/cisloPeriodika
  • 15 December 2013
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 78467
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11320/13:10189245
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Nuclear reaction analysis; Electrical resistivity; Diffusion; Hydrogen; ZnO (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [B4962E829856]
http://linked.open...i/riv/nazevZdroje
  • Journal of Alloys and Compounds
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 580
http://linked.open...iv/tvurceVysledku
  • Lukáč, František
  • Melikhova, Oksana
  • Vlček, Marián
  • Čížek, Jakub
  • Rogalla, D.
  • Traeger, F.
  • Becker, H. -W.
http://linked.open...ain/vavai/riv/wos
  • 000328172400015
issn
  • 0925-8388
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jallcom.2013.02.075
http://localhost/t...ganizacniJednotka
  • 11320
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