About: Study of the speciation in the system UO22+ - SO42- - H2O by means of the UV-VIS spectrophotometry     Goto   Sponge   NotDistinct   Permalink

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  • This work estimates speciation characteristics of the UO22+ - SO42- - H2O system by means of the analysis of UV-VIS absorption spectra of series of aqueous solutions of uranium(VI) (total molar concentration 0.05 mol.dm-3), sodium sulfate (varying concentration from 0 to 1.3 mol.dm-3), perchloric acid (to adjust pH = 2) and sodium perchlorate (to adjust ionic strength I in each series (between different series I varied from 0.7 mol.Kg-1 to 4.0 mol.Kg-1)). Properties of several complexes were estimated by SVD-based mathematical analysis of spectra. The existence of isomers of uranyl(VI)-sulfate complexes is discussed.
  • This work estimates speciation characteristics of the UO22+ - SO42- - H2O system by means of the analysis of UV-VIS absorption spectra of series of aqueous solutions of uranium(VI) (total molar concentration 0.05 mol.dm-3), sodium sulfate (varying concentration from 0 to 1.3 mol.dm-3), perchloric acid (to adjust pH = 2) and sodium perchlorate (to adjust ionic strength I in each series (between different series I varied from 0.7 mol.Kg-1 to 4.0 mol.Kg-1)). Properties of several complexes were estimated by SVD-based mathematical analysis of spectra. The existence of isomers of uranyl(VI)-sulfate complexes is discussed. (en)
Title
  • Study of the speciation in the system UO22+ - SO42- - H2O by means of the UV-VIS spectrophotometry
  • Study of the speciation in the system UO22+ - SO42- - H2O by means of the UV-VIS spectrophotometry (en)
skos:prefLabel
  • Study of the speciation in the system UO22+ - SO42- - H2O by means of the UV-VIS spectrophotometry
  • Study of the speciation in the system UO22+ - SO42- - H2O by means of the UV-VIS spectrophotometry (en)
skos:notation
  • RIV/00216208:11320/11:10106089!RIV13-MSM-11320___
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  • S, Z(MSM0021620835), Z(MSM6840770020)
http://linked.open...vai/riv/dodaniDat
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  • 233145
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  • RIV/00216208:11320/11:10106089
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  • spectrophotometry; UV-VIS; UO22+; Speciation (en)
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  • [37C4D6F59233]
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  • Freiberg, Německo
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  • Berlin
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  • The New Uranium Mining Boom
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  • Štamberg, Karel
  • Vetešník, Aleš
  • Bok, Jiří
  • Višňák, Jakub
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number of pages
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  • 10.1007/978-3-642-22122-4_74
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  • SPRINGER
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  • 978-3-642-22121-7
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  • 11320
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