About: Electronic structure and hyperfine fields in non-stoichiometric magnetite above the Verwey transition     Goto   Sponge   NotDistinct   Permalink

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  • The NMR spectra of 57Fe nuclei were measured below and above the Verwey transition temperature in single crystal samples of Fe3(1-d)O4( 0{d{0.009). The measured crystals were grown from the melt using the cold crucible technique. In a cubic phase above Verwey transition the satellite structure induced by vacancies in the octahedral sublattice is clearly resolved. The satellite lines originate from those iron nuclei in the tetrahedral sublattice that are nearest to the vacancy. Temperature dependence of satellite lines indicates that the presence of vacancy leads to a redistribution of the electrons in octahedral sublattice and the appearance of iron ions possessing appreciable orbital momentum.
  • The NMR spectra of 57Fe nuclei were measured below and above the Verwey transition temperature in single crystal samples of Fe3(1-d)O4( 0{d{0.009). The measured crystals were grown from the melt using the cold crucible technique. In a cubic phase above Verwey transition the satellite structure induced by vacancies in the octahedral sublattice is clearly resolved. The satellite lines originate from those iron nuclei in the tetrahedral sublattice that are nearest to the vacancy. Temperature dependence of satellite lines indicates that the presence of vacancy leads to a redistribution of the electrons in octahedral sublattice and the appearance of iron ions possessing appreciable orbital momentum. (en)
Title
  • Electronic structure and hyperfine fields in non-stoichiometric magnetite above the Verwey transition
  • Electronic structure and hyperfine fields in non-stoichiometric magnetite above the Verwey transition (en)
skos:prefLabel
  • Electronic structure and hyperfine fields in non-stoichiometric magnetite above the Verwey transition
  • Electronic structure and hyperfine fields in non-stoichiometric magnetite above the Verwey transition (en)
skos:notation
  • RIV/00216208:11320/10:10057079!RIV11-GA0-11320___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA202/08/0541), S, Z(AV0Z10100521), Z(MSM0021620834)
http://linked.open...iv/cisloPeriodika
  • 9-12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...dnocenehoVysledku
  • 256781
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11320/10:10057079
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • transition; Verwey; magnetite; hyperfine fields; Electronic structure (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [25A9AA639D89]
http://linked.open...i/riv/nazevZdroje
  • Journal of Magnetism and Magnetic Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 322
http://linked.open...iv/tvurceVysledku
  • Novák, Pavel
  • Štěpánková, Helena
  • Chlan, Vojtěch
  • Řezníček, Richard
  • Kouřil, Karel
http://linked.open...ain/vavai/riv/wos
  • 000275746100010
http://linked.open...n/vavai/riv/zamer
issn
  • 0304-8853
number of pages
http://localhost/t...ganizacniJednotka
  • 11320
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