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  • Crystal structure and magnetic properties of CeNiH3.7 were studied by the means of the powder X-ray diffraction, specific heat, and dc and ac magnetization techniques. It was established that hydrogenation stabilizes the Ce valence and turns CeNi-H into a dilute Kondo system with TK = 3.7 K. The Kondo screening in CeNiH3.7 is suppressed by the applied magnetic field, although it still affects the properties of CeNiH3.7 at 14 T, as indicated by the enhanced g-coefficient of electronic specific heat, which remains more than 2 times larger compared to the precursor compound CeNi. Its zero-field value is as high as 1890 mJ/(mol K2). Hydrogenation acts primarily as the negative pressure agent in CeNiH3.7, while the role of H-metal bonding is secondary.
  • Crystal structure and magnetic properties of CeNiH3.7 were studied by the means of the powder X-ray diffraction, specific heat, and dc and ac magnetization techniques. It was established that hydrogenation stabilizes the Ce valence and turns CeNi-H into a dilute Kondo system with TK = 3.7 K. The Kondo screening in CeNiH3.7 is suppressed by the applied magnetic field, although it still affects the properties of CeNiH3.7 at 14 T, as indicated by the enhanced g-coefficient of electronic specific heat, which remains more than 2 times larger compared to the precursor compound CeNi. Its zero-field value is as high as 1890 mJ/(mol K2). Hydrogenation acts primarily as the negative pressure agent in CeNiH3.7, while the role of H-metal bonding is secondary. (en)
Title
  • Effect of Hydrogenation on Magnetic Interactions in CeNi (Article No. 446003)
  • Effect of Hydrogenation on Magnetic Interactions in CeNi (Article No. 446003) (en)
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  • Effect of Hydrogenation on Magnetic Interactions in CeNi (Article No. 446003)
  • Effect of Hydrogenation on Magnetic Interactions in CeNi (Article No. 446003) (en)
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  • RIV/00216208:11320/09:00206516!RIV10-GA0-11320___
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  • P(GA202/07/0418), Z(MSM0021620834)
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  • Effect; Hydrogenation; Magnetic; Interactions; Article; 446003 (en)
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  • [C172298085EF]
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  • Journal of Physics: Condensed Matter
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  • 21
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  • Havela, Ladislav
  • Pospíšil, Jiří
  • Kolomiyets, Oleksandr
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  • 000270853100019
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