About: Facile Synthesis of an Extensive Family of Sc2O@C2n (n = 35-47) and Chemical Insight into the Smallest Member of Sc2O@C2(7892)-C70

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About: Facile Synthesis of an Extensive Family of Sc2O@C2n (n = 35-47) and Chemical Insight into the Smallest Member of Sc2O@C2(7892)-C70 Goto Sponge NotDistinct Permalink

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Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://pubs.acs.org/doi/pdf/10.1021/jp509975w
Description	An extensive family of oxide cluster fullerenes (OCFs) Sc2O@C(2)n (n = 35-47) has been facilely produced for the first time by introducing CO2 as the oxygen source. Among this family, Sc2O@C-70 was identified as the smallest OCF and therefore isolated and characterized by mass spectrometry, Sc-45 nuclear magnetic resonance, UV-vis-near-infrared absorption spectroscopy, cyclic voltammetry, and density functional theory calculations. The combined experimental and computational studies reveal a non-isolated pentagon rule isomer Sc2O@C-2(7892)-C-70 with reversible oxidative behavior and lower bandgap relative to that of Sc2S@C-2(7892)-C-70, demonstrating a typical example of unexplored OCF and underlining its cluster-dependent electronic properties. An extensive family of oxide cluster fullerenes (OCFs) Sc2O@C(2)n (n = 35-47) has been facilely produced for the first time by introducing CO2 as the oxygen source. Among this family, Sc2O@C-70 was identified as the smallest OCF and therefore isolated and characterized by mass spectrometry, Sc-45 nuclear magnetic resonance, UV-vis-near-infrared absorption spectroscopy, cyclic voltammetry, and density functional theory calculations. The combined experimental and computational studies reveal a non-isolated pentagon rule isomer Sc2O@C-2(7892)-C-70 with reversible oxidative behavior and lower bandgap relative to that of Sc2S@C-2(7892)-C-70, demonstrating a typical example of unexplored OCF and underlining its cluster-dependent electronic properties. (en)
Title	Facile Synthesis of an Extensive Family of Sc2O@C2n (n = 35-47) and Chemical Insight into the Smallest Member of Sc2O@C2(7892)-C70 Facile Synthesis of an Extensive Family of Sc2O@C2n (n = 35-47) and Chemical Insight into the Smallest Member of Sc2O@C2(7892)-C70 (en)
skos:prefLabel	Facile Synthesis of an Extensive Family of Sc2O@C2n (n = 35-47) and Chemical Insight into the Smallest Member of Sc2O@C2(7892)-C70 Facile Synthesis of an Extensive Family of Sc2O@C2n (n = 35-47) and Chemical Insight into the Smallest Member of Sc2O@C2(7892)-C70 (en)
skos:notation	RIV/00216208:11310/14:10284420!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GAP208/10/1724)
http://linked.open...iv/cisloPeriodika	49
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Uhlík, Filip
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	16313
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/14:10284420
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	functionalization; carbon; cluster; solid c-60; metal atoms; molecular-hydrogen; structural-characterization; endohedral metallofullerenes; c-82 fullerene cage; isolated pentagon rule (en)
http://linked.open.../riv/klicoveSlovo	functionalization endohedral metallofullerenes cluster structural-characterization carbon molecular-hydrogen c-82 fullerene cage isolated pentagon rule metal atoms solid c-60
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[18196AC4A443]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry C
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	10 (xsd:int)
http://linked.open...vavai/riv/projekt	Molecular simulation studies of structure and dynamics of ice surfaces in the presence of impurities and atmospheric pollutants
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	118
http://linked.open...iv/tvurceVysledku	Uhlík, Filip Slanina, Zdenek Feng, Lai Hao, Yajuan Chen, Ning Cong, Hailin Li, Xiaohong Wan, Yingbo Yang, Ting Zhang, Meirong
http://linked.open...ain/vavai/riv/wos	000346321700063
issn	1932-7447
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/jp509975w
http://localhost/t...ganizacniJednotka	11310

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