About: Recognition of chiral anions using calix[4]arene-based ureido receptor in the 1,3-alternate conformation     Goto   Sponge   NotDistinct   Permalink

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Description
  • A new type of calixarene-based receptor designed for the recognition of chiral anions was prepared by the introduction of (S)-2-methylbutan-l-ol moieties into the lower rim of calixarene. The immobilization of calixarene skeleton in the 1,3-alternate conformation enabled the construction of a cavity consisting of preorganised ureido functions and chiral substituents in close proximity. This cavity is capable of chiral discrimination of selected anions as demonstrated on D- and L-phenylalaninates.
  • A new type of calixarene-based receptor designed for the recognition of chiral anions was prepared by the introduction of (S)-2-methylbutan-l-ol moieties into the lower rim of calixarene. The immobilization of calixarene skeleton in the 1,3-alternate conformation enabled the construction of a cavity consisting of preorganised ureido functions and chiral substituents in close proximity. This cavity is capable of chiral discrimination of selected anions as demonstrated on D- and L-phenylalaninates. (en)
Title
  • Recognition of chiral anions using calix[4]arene-based ureido receptor in the 1,3-alternate conformation
  • Recognition of chiral anions using calix[4]arene-based ureido receptor in the 1,3-alternate conformation (en)
skos:prefLabel
  • Recognition of chiral anions using calix[4]arene-based ureido receptor in the 1,3-alternate conformation
  • Recognition of chiral anions using calix[4]arene-based ureido receptor in the 1,3-alternate conformation (en)
skos:notation
  • RIV/00216208:11310/14:10277919!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 41601
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/14:10277919
http://linked.open...riv/jazykVysledku
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  • anion recognition; chiral receptor; NMR titration; alkylation; calixarene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [4D3776901310]
http://linked.open...i/riv/nazevZdroje
  • Tetrahedron
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http://linked.open...UplatneniVysledku
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  • 70
http://linked.open...iv/tvurceVysledku
  • Budka, Jan
  • Císařová, Ivana
  • Lhoták, Pavel
  • Eigner, Václav
  • Hudeček, Oldřich
  • Vrzal, Lukáš
  • Botha, Filip
http://linked.open...ain/vavai/riv/wos
  • 000330816000043
issn
  • 0040-4020
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tet.2013.11.030
http://localhost/t...ganizacniJednotka
  • 11310
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