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Description
  • The structure of doubly ionized benzene has been spectroscopically studied for the first time. Helium-tagged complexes were prepared at temperatures below 4 K and analyzed using infrared predissociation spectroscopy. Double ionization of benzene yields primarily high-energy dications with a six-membered-ring structure. Some of the dications undergo rearrangement to a more stable pyramidal isomer with a C5H5 base and CH at the apex. By means of isomer-selective heating by a CO2 laser, infrared predissociation spectra of both the classical and pyramidal dications were obtained.
  • The structure of doubly ionized benzene has been spectroscopically studied for the first time. Helium-tagged complexes were prepared at temperatures below 4 K and analyzed using infrared predissociation spectroscopy. Double ionization of benzene yields primarily high-energy dications with a six-membered-ring structure. Some of the dications undergo rearrangement to a more stable pyramidal isomer with a C5H5 base and CH at the apex. By means of isomer-selective heating by a CO2 laser, infrared predissociation spectra of both the classical and pyramidal dications were obtained. (en)
Title
  • Probing Isomers of the Benzene Dication in a Low-Temperature Trap
  • Probing Isomers of the Benzene Dication in a Low-Temperature Trap (en)
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  • Probing Isomers of the Benzene Dication in a Low-Temperature Trap
  • Probing Isomers of the Benzene Dication in a Low-Temperature Trap (en)
skos:notation
  • RIV/00216208:11310/14:10271745!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita
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  • I
http://linked.open...iv/cisloPeriodika
  • 8
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  • 39695
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  • RIV/00216208:11310/14:10271745
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  • ar; ions; cations; spectrum; dynamics; complexes; carbocations; chemistry; protonated benzene; infrared-spectroscopy (en)
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  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [08DDF60EB780]
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  • Journal of the American Chemical Society
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http://linked.open...v/svazekPeriodika
  • 136
http://linked.open...iv/tvurceVysledku
  • Gerlich, Dieter
  • Roithová, Jana
  • Jašík, Juraj
http://linked.open...ain/vavai/riv/wos
  • 000332144300007
issn
  • 0002-7863
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/ja412109h
http://localhost/t...ganizacniJednotka
  • 11310
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