About: Organocatalytic enantioselective allylic alkylation of MBH carbonates with beta-keto esters     Goto   Sponge   NotDistinct   Permalink

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Description
  • The highly stereoselective allylic alkylation of Morita-Baylis-Hillman carbonates with beta-ketoesters catalysed by beta-ICD is described. The corresponding products containing two adjacent quaternary and tertiary carbon centers were obtained in good yields with high diastereoselectivity (up to 10 : 1 dr) and enantio-selectivity (up to 95% ee).
  • The highly stereoselective allylic alkylation of Morita-Baylis-Hillman carbonates with beta-ketoesters catalysed by beta-ICD is described. The corresponding products containing two adjacent quaternary and tertiary carbon centers were obtained in good yields with high diastereoselectivity (up to 10 : 1 dr) and enantio-selectivity (up to 95% ee). (en)
Title
  • Organocatalytic enantioselective allylic alkylation of MBH carbonates with beta-keto esters
  • Organocatalytic enantioselective allylic alkylation of MBH carbonates with beta-keto esters (en)
skos:prefLabel
  • Organocatalytic enantioselective allylic alkylation of MBH carbonates with beta-keto esters
  • Organocatalytic enantioselective allylic alkylation of MBH carbonates with beta-keto esters (en)
skos:notation
  • RIV/00216208:11310/14:10271738!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, S
http://linked.open...iv/cisloPeriodika
  • 28
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 35139
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/14:10271738
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • phosphine oxides; vicinal tertiary; gamma-butenolides; kinetic resolution; adjacent quaternary; tertiary stereocenters; stereoselective construction; asymmetric phase-transfer; quaternary stereogenic centers; baylis-hillman carbonates (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [2131CB1F3F46]
http://linked.open...i/riv/nazevZdroje
  • Organic and Biomolecular Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 12
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Hybelbauerová, Simona
  • Veselý, Jan
  • Kamlar, Martin
http://linked.open...ain/vavai/riv/wos
  • 000338432100002
issn
  • 1477-0520
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c4ob00682h
http://localhost/t...ganizacniJednotka
  • 11310
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