About: Synthesis and characterization of ferrocenyl camphor compounds

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1016/j.jorganchem.2013.11.039
Description	Several ferrocene camphor compounds of the general formula FcCONHR, where Fc ferrocenyl and R is N(C10H13NSO2) (2), N(C10H14O) (3), N(C10H16) (4) or NLiCO(C10H14O) (6), were synthesized by the reaction of FcCONHNH(2) (1) with the respective camphor derivatives. In the resulting compounds, the ferrocene and camphor units are connected via a hydrazone link formed through condensation of the terminal NH2 group in 1 and the carbonyl group of the camphor derivative. The characterization of the complexes is based mostly on analytical data and on NMR and IR spectra. Additional insight into the structural characteristics of complex (E)-FcCONHN(C10H14O) (3) was obtained from variable temperature and 2D NMR measurements while computational calculations were used to assign the bands in IR spectra of FcCONHN(C10H13NSO2) isomers. X-ray diffraction analysis has shown that the molecules of (E)-FcCONHN(C10H13NSO2) associate into symmetric dimers in the solid state via NeH/O hydrogen bonds between the hydrazone moieties. Several ferrocene camphor compounds of the general formula FcCONHR, where Fc ferrocenyl and R is N(C10H13NSO2) (2), N(C10H14O) (3), N(C10H16) (4) or NLiCO(C10H14O) (6), were synthesized by the reaction of FcCONHNH(2) (1) with the respective camphor derivatives. In the resulting compounds, the ferrocene and camphor units are connected via a hydrazone link formed through condensation of the terminal NH2 group in 1 and the carbonyl group of the camphor derivative. The characterization of the complexes is based mostly on analytical data and on NMR and IR spectra. Additional insight into the structural characteristics of complex (E)-FcCONHN(C10H14O) (3) was obtained from variable temperature and 2D NMR measurements while computational calculations were used to assign the bands in IR spectra of FcCONHN(C10H13NSO2) isomers. X-ray diffraction analysis has shown that the molecules of (E)-FcCONHN(C10H13NSO2) associate into symmetric dimers in the solid state via NeH/O hydrogen bonds between the hydrazone moieties. (en)
Title	Synthesis and characterization of ferrocenyl camphor compounds Synthesis and characterization of ferrocenyl camphor compounds (en)
skos:prefLabel	Synthesis and characterization of ferrocenyl camphor compounds Synthesis and characterization of ferrocenyl camphor compounds (en)
skos:notation	RIV/00216208:11310/14:10218535!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GAP207/11/0705)
http://linked.open...iv/cisloPeriodika	Neuveden
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Schulz, Jiří Štěpnička, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	48969
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/14:10218535
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	hydrogen bridging; E,Z Isomers; ferrocene; camphor (en)
http://linked.open.../riv/klicoveSlovo	camphor ferrocene E Z Isomers hydrogen bridging
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[41D10B25A89A]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Carborane-modified iron-arene complexes
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	760
http://linked.open...iv/tvurceVysledku	Schulz, Jiří Štěpnička, Petr Carvalho, M. Fernanda N. N. Ferreira, Ana S. D. Galvao, Adelino M. Roseiro, Alexandra P. S. Veiros, Luis F.
http://linked.open...ain/vavai/riv/wos	000334295800016
issn	0022-328X
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jorganchem.2013.11.039
http://localhost/t...ganizacniJednotka	11310

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