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  • The calix diastereoisomers of the parallel tris-Troger's base (tris-TB) derivatives were suggested as potential cavitands in 2002, and the first members of this cavitand family were introduced in 2007. The synthetic strategy enabling the preparation of naphthalene and anthracene derivatives of parallel tris-TBs, i.e. preparation without any reduction step, is introduced. Naphthalene calix-tris-TB derivative having a cavity volume of about 0.113 nm(3) (65% of alpha-CD cavity) is prepared by isomerisation in various acid conditions.
  • The calix diastereoisomers of the parallel tris-Troger's base (tris-TB) derivatives were suggested as potential cavitands in 2002, and the first members of this cavitand family were introduced in 2007. The synthetic strategy enabling the preparation of naphthalene and anthracene derivatives of parallel tris-TBs, i.e. preparation without any reduction step, is introduced. Naphthalene calix-tris-TB derivative having a cavity volume of about 0.113 nm(3) (65% of alpha-CD cavity) is prepared by isomerisation in various acid conditions. (en)
Title
  • A new synthetic strategy to prepare throne and calix diastereoisomers of parallel tris-Troger's bases
  • A new synthetic strategy to prepare throne and calix diastereoisomers of parallel tris-Troger's bases (en)
skos:prefLabel
  • A new synthetic strategy to prepare throne and calix diastereoisomers of parallel tris-Troger's bases
  • A new synthetic strategy to prepare throne and calix diastereoisomers of parallel tris-Troger's bases (en)
skos:notation
  • RIV/00216208:11310/12:10123362!RIV13-MSM-11310___
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  • I
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  • 2
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  • 120417
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  • RIV/00216208:11310/12:10123362
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  • cavitand; diastereoisomerisation; parallel tris-Troger's base; family; analogs; chemistry; bis-trogers (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [58364AD8610F]
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  • Supramolecular Chemistry
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  • 24
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Král, Vladimír
  • Havlík, Martin
  • Dolenský, Bohumil
  • Kessler, Jiří
http://linked.open...ain/vavai/riv/wos
  • 000303569700007
issn
  • 1061-0278
number of pages
http://bibframe.org/vocab/doi
  • 10.1080/10610278.2011.632822
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  • 11310
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