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Description
  • In this study, a new complementary approach was employed for the determination of stoichiometry in 10 iron-chelating agents, including clinically used drugs, by UV-Vis spectrophotometry at relevant pH conditions and compared with the standard Job's method. We reported that this approach was able to determine the stoichiometry in all tested cases. The major benefit of this method compared to the standard Job's approach seems to be its capability to reveal a reaction stoichiometry in chelators with moderate affinity to iron.
  • In this study, a new complementary approach was employed for the determination of stoichiometry in 10 iron-chelating agents, including clinically used drugs, by UV-Vis spectrophotometry at relevant pH conditions and compared with the standard Job's method. We reported that this approach was able to determine the stoichiometry in all tested cases. The major benefit of this method compared to the standard Job's approach seems to be its capability to reveal a reaction stoichiometry in chelators with moderate affinity to iron. (en)
Title
  • Mathematical calculations of iron complex stoichiometry by direct UV-Vis spectrophotometry
  • Mathematical calculations of iron complex stoichiometry by direct UV-Vis spectrophotometry (en)
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  • Mathematical calculations of iron complex stoichiometry by direct UV-Vis spectrophotometry
  • Mathematical calculations of iron complex stoichiometry by direct UV-Vis spectrophotometry (en)
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  • RIV/00216208:11160/13:10144043!RIV14-MSM-11160___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, S
http://linked.open...iv/cisloPeriodika
  • August
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 86565
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11160/13:10144043
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Spectrophotometry; Stoichiometry; Job's method; Complex; Chelator; Iron (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [3A1D6AA7A47F]
http://linked.open...i/riv/nazevZdroje
  • Bioorganic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...v/svazekPeriodika
  • 49
http://linked.open...iv/tvurceVysledku
  • Vávrová, Kateřina
  • Filipský, Tomáš
  • Hrdina, Radomír
  • Mladěnka, Přemysl
  • Říha, Michal
http://linked.open...ain/vavai/riv/wos
  • 000324317600001
issn
  • 0045-2068
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.bioorg.2013.06.002
http://localhost/t...ganizacniJednotka
  • 11160
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