About: Phosphide solid solutions within the metal-rich section of the quaternary system, Co-Fe-Ni-P at 800 oC, and their mineralogical implications

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About: Phosphide solid solutions within the metal-rich section of the quaternary system, Co-Fe-Ni-P at 800 oC, and their mineralogical implications Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Fázové vztahy v soustavě Co-Fe-Ni-P byly studovány v zatavených, evakuovaných kamenných trubicích. V soustavě byly zjištěny 3 rozsáhlé pevné roztoky:tetragonální(Co,Ni,Fe)3P, hexagonální (Co,Ni,Fe)2P, a orthorombický (Co,Ni,Fe)2P (cs) Solid solutions within the Co-Fe-Ni-P system were studied experimentally by means of the evacuated silica tube technique at 800 oC. Three broad solid solutions were detected in the system, tetragonal f (Co,Ni,Fe)3P, hexagonal l1 (Co,Ni,Fe)2P, and orthorhombic l2 (Co,Ni,Fe)2P . Within these three pseudoternary systems, all phosphides known as minerals are situated. Cobalt has a remarkable influence on the structure type of (Co,Fe,Ni)2P solid solutions, inducing a transition of the hexagonal structure (Fe-Ni rich) to orthorhombic (Co rich). Nevertheless, the cobalt content reported in allabogdanite is too low to bring about the transition of the hexagonal l1 structure to the orthorhombic l2 structure. In addition to these most important solid solutions, two binary solid solutions were detected: tetragonal (Co,Ni)12P5 and a very narrow, (Co,Ni,)5P2 , which is hexagonal. Phosphides with such compositions can be expected in meteorites, in close association with other phosphides. Solid solutions within the Co-Fe-Ni-P system were studied experimentally by means of the evacuated silica tube technique at 800 oC. Three broad solid solutions were detected in the system, tetragonal f (Co,Ni,Fe)3P, hexagonal l1 (Co,Ni,Fe)2P, and orthorhombic l2 (Co,Ni,Fe)2P . Within these three pseudoternary systems, all phosphides known as minerals are situated. Cobalt has a remarkable influence on the structure type of (Co,Fe,Ni)2P solid solutions, inducing a transition of the hexagonal structure (Fe-Ni rich) to orthorhombic (Co rich). Nevertheless, the cobalt content reported in allabogdanite is too low to bring about the transition of the hexagonal l1 structure to the orthorhombic l2 structure. In addition to these most important solid solutions, two binary solid solutions were detected: tetragonal (Co,Ni)12P5 and a very narrow, (Co,Ni,)5P2 , which is hexagonal. Phosphides with such compositions can be expected in meteorites, in close association with other phosphides. (en)
Title	Phosphide solid solutions within the metal-rich section of the quaternary system, Co-Fe-Ni-P at 800 oC, and their mineralogical implications Pevné roztoky fosfidů v kovy bohaté části soustavy Co-Fe-Ni-P při 800 oC a jejich mineralogická aplikace. (cs) Phosphide solid solutions within the metal-rich section of the quaternary system, Co-Fe-Ni-P at 800 oC, and their mineralogical implications (en)
skos:prefLabel	Phosphide solid solutions within the metal-rich section of the quaternary system, Co-Fe-Ni-P at 800 oC, and their mineralogical implications Pevné roztoky fosfidů v kovy bohaté části soustavy Co-Fe-Ni-P při 800 oC a jejich mineralogická aplikace. (cs) Phosphide solid solutions within the metal-rich section of the quaternary system, Co-Fe-Ni-P at 800 oC, and their mineralogical implications (en)
skos:notation	RIV/00025798:_____/06:00000200!RIV07-GA0-00025798
http://linked.open.../vavai/riv/strany	399-408
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA205/05/0459)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2007
http://linked.open...aciTvurceVysledku	Drábek, Milan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Česká geologická služba
http://linked.open...dnocenehoVysledku	491987
http://linked.open...ai/riv/idVysledku	RIV/00025798:_____/06:00000200
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	phase relations, phosphides, schreibersite, nickelphosphide, barringerite, allabogdanite, Co, Fe, Ni (en)
http://linked.open.../riv/klicoveSlovo	Co phase relations schreibersite Fe Ni nickelphosphide phosphides allabogdanite barringerite
http://linked.open...odStatuVydavatele	CA - Kanada
http://linked.open...ontrolniKodProRIV	[67CD5C655975]
http://linked.open...i/riv/nazevZdroje	Canadian Mineralogist
http://linked.open...in/vavai/riv/obor	DB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	1 (xsd:int)
http://linked.open...vavai/riv/projekt	The system Os-Mo-S and its geological application
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	44
http://linked.open...iv/tvurceVysledku	Drábek, Milan
issn	0008-4476
number of pages	10 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Phosphide solid solutions within the metal-rich section of the quaternary system, Co-Fe-Ni-P at 800 oC, and their mineralogical implications Phosphide solid solutions within the metal-rich section of the quaternary system, Co-Fe-Ni-P at 800 oC, and their mineralogical implications

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